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Molecularly Imprinted Poly(N-Vinyl Imidazole) Based Polymers Grafted onto Nonwoven Fabrics for Recognition/Removal of Phloretic Acid

13-05-2013 | Author(s): Ma. Llorina Rañada , Meshude Akbulut , Lucille Abad , Olgun Güven, Radiation Physics and Chemistry, 2013

Publication date: Available online 10 May 2013 Source:Radiation Physics and Chemistry Author(s): Ma. Llorina Rañada , Meshude Akbulut , Lucille Abad , Olgun Güven A solution of N-vinyl imidazole (VIm), ethylene glycol dimethylacrylate (EGDMA), and phloretic acid ...

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Synthesis of a Novel Imprinted Polymeric Material for Simultaneous Recognition of Methamidophos and Acephate

08-05-2013 | Xilong Wang, Limin Zhang, Mingxiao Li, Zhixiang Xu, Advances in Polymer Technology, 2013

ABSTRACT In this study, a novel molecularly imprinted polymer was synthesized using acephate as the template molecule, methacrylic acid as the functional monomer, and ethylene glycol dimethacrylate as the cross‐linker. The imprinted polymer was characterized by the static adsorption ...

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Cucurbit[8]uril-based supramolecular polymers: promoting supramolecular polymerization by metal-coordination

08-05-2013 | Yiliu Liu; Zehuan Huang; Xinxin Tan; Zhiqiang Wang; Xi Zhang, Chemical Communication, 2013

Linear supramolecular polymers were obtained in aqueous solution by employing cucurbit[8]uril-based host-guest interaction as the driving force. Water-soluble monomers were prepared through directly metal-coordination. The rigid and bulky terpyridine-Fe linker can effectively enhance the ...

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Improving Secondary Ion Mass Spectrometry C60n+ Sputter Depth Profiling of Challenging Polymers with Nitric Oxide Gas Dosing

08-05-2013 | R. Havelund; A. Licciardello; J. Bailey; N. Tuccitto; D. Sapuppo; I. S. Gilmore; J. S. Sharp; J. L. S. Lee; T. Mouhi ..., Analytical Chemistry, 2013

Organic depth profiling using secondary ion mass spectrometry (SIMS) provides valuable information about the three-dimensional distribution of organic molecules. However, for a range of materials, commonly used cluster ion beams such as C60n+ do not yield useful depth profiles. A promising ...

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Polymer-Assisted Synthesis of Colloidal Germanium Telluride Nano-Octahedra, Nanospheres, and Nanosheets

07-05-2013 | Matthew R. Buck; Adam J. Biacchi; Eric J. Popczun; Raymond E. Schaak, Chemistry of Materials, 2013

Germanium telluride (GeTe) nanostructures are a demonstrated platform for studying the effects of scaling on reversible, amorphous-to-crystalline phase transitions that are important for data storage and computing applications, and for understanding ferroelectric behavior at the nanometer ...

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Influence of the environment on swelling of hydrophilic polymers

06-05-2013 | Author(s): Nikolai B. Ferapontov , Mikhail G. Tokmachev , Aleksander N. Gagarin , Nadezda L. Strusovskaya , Svet ..., Reactive and Functional Polymers, 2013

Publication date: Available online 30 April 2013Source:Reactive and Functional Polymers Author(s): Nikolai B. Ferapontov , Mikhail G. Tokmachev , Aleksander N. Gagarin , Nadezda L. Strusovskaya , Svetlana N. Khudyakova The influence of water activity on swelling of cross-linked ...

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Computer Simulation of Fifth Generation Dendronized Polymers: Impact of Charge on Internal Organization

06-05-2013 | Oscar Bertran; Baozhong Zhang; A. Dieter Schlüter; Martin Kröger; Carlos Alemán, Journal of Physical Chemistry B, 2013

The internal organization of a fifth-generation dendronized polymer (PG5) has been investigated by atomistic molecular dynamics simulations in a vacuum. This study reveals an exceptional behavior of PG5 within the homologous series of g-generation PGg polymers. Three molecular configurations, ...

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Mechanical Reinforcement of Polybenzoxazole by Carbon Nanotubes through Noncovalent Functionalization

06-05-2013 | Takahiro Fukumaru; Tsuyohiko Fujigaya; Naotoshi Nakashima, Macromolecules, 2013

Polybenzoxazole (PBO) reinforced with carbon nanotubes (CNTs) is of great interest in the field of polymer composites because PBO and CNTs possess the highest-level mechanical properties among polymers and filler materials, respectively. However, the insolubility of PBO and the CNTs makes it ...

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Solution-Based Single Molecule Imaging of Surface-Immobilized Conjugated Polymers

03-05-2013 | Paul A. Dalgarno; Christopher A. Traina; J. Carlos Penedo; Guillermo C. Bazan; Ifor D. W. Samuel, Journal of the American Chemical Society, 2013

The photophysical behavior of conjugated polymers used in modern optoelectronic devices is strongly influenced by their structural dynamics and conformational heterogeneity, both of which are dependent on solvent properties. Single molecule studies of these polymer systems embedded in a host ...

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Facile and controllable incorporation of gold nanoparticles within one-dimensional self-assemblies of hyperbranched polymers

01-05-2013 | Haiqing Li; Justin J. Cooper-White; Il Kim, Soft Matter, 2013

Using a mono-pyrene terminated hyperbranched polyglycidol (mPTHP) as a building block, one-dimensional (1D) mPTHP and mPTHP/gold nanoparticle (Au NP) nanostructures are fabricated in the presence of HAuCl4. By simply mixing mPTHP and different concentrations of aqueous HAuCl4 solution at room ...

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