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Thianthrene-functionalized polynorbornenes as high-voltage materials for organic cathode-based dual-ion batteries

28-Jul-2015 | Martin Erich Speer; Martin Kolek; Jean Jacques Jassoy; Jennifer Heine; Martin Winter; Peter Maria Bieker; Birgit Esser, Chemical Communication, 2015

Thianthrene-functionalized polynorbornenes were investigated as high-voltage organic cathode materials for dual-ion cells. The polymers show reversible oxidation reactions in solution and as a solid in composite electrodes. Constant current investigations displayed a capacity of up to 66 mAh g-1 ...


Magnetic molecularly imprinted polymers synthesized by surface‐initiated reversible addition‐fragmentation chain transfer polymerization for the enrichment and determination of synthetic estrogens in aqueous solution

23-Jul-2015 | Fangfang Chen, Jingjing Zhang, Minjun Wang, Jie Kong, Journal of Separation Science, 2015

J. Sep. Sci. 2015, 38, 2670–2676 DOI: 10.1002/jssc.201500407 The novel magnetic molecularly imprinted polymers for enrichment of synthetic estrogens were synthesized via surface‐initiated reversible addition addition‐fragmentation chain transfer polymerization using diethylstilbestrol ...


Microfluidic Crystal Engineering of π-Conjugated Polymers

22-Jul-2015 | Gang Wang; Nils Persson; Ping-Hsun Chu; Nabil Kleinhenz; Boyi Fu; Mincheol Chang; Nabankur Deb; Yimin Mao; Hongzhi W ..., ACS Nano, 2015

Very few studies have reported oriented crystallization of conjugated polymers directly in solution. Here, solution crystallization of conjugated polymers in a microfluidic system is found to produce tightly π-stacked fibers with commensurate improved charge transport characteristics. For ...


Electrospinning of p‐Aramid Fibers

21-Jul-2015 | Jian Yao, Junhong Jin, Emiliano Lepore, Nicola M. Pugno, Cees W.M. Bastiaansen, Ton Peijs, Macromolecular Materials and Engineering, 2015

Electrospun poly (p‐phenylene terephthalamide) (PPTA) fibers with diameters between 275 nm and 15 µm were obtained from anisotropic solutions, albeit that the spinning process was difficult to control. Key solution parameters like conductivity, surface tension, and viscosity were used to ...


(3E,8E)-3,8-Bis(2-oxoindolin-3-ylidene)naphtho-[1,2-b:5,6-b’]difuran-2,7(3H,8H)-dione (INDF) based polymers for organic thin-film transistors with highly balanced ambipolar charge transport characteristics

21-Jul-2015 | Yunfeng Deng; Bin Sun; Yinghui He; Jesse Quinn; Chang Guo; Yuning Li, Chemical Communication, 2015

Two donor-acceptor (D-A) conjugated polymers, PINDFTT and PINDFBT, based on a novel electron acceptor, (3E,8E)-3,8-Bis(2-oxoindolin-3-ylidene)naphtho-[1,2-b:5,6-b’]difuran-2,7(3H,8H)-dione (INDF), are synthesized for solution processed organic thin- film transistors. Both polymers exhibited ...


Interaction of Hyaluronan with Cationic Nanoparticles

20-Jul-2015 | Fouzia Bano; Mónica Carril; Paolo Di Gianvincenzo; Ralf P. Richter, Langmuir, 2015

The polysaccharide hyaluronan (HA) is a main component of peri- and extracellular matrix, and an attractive molecule for materials design in tissue engineering and nanomedicine. Here, we study the morphology of complexes that form upon interaction of nanometer-sized amine-coated gold particles ...


Effect of temperature on the dissolution and thermal alteration of combined amino acids fixed in natural sediment under simulated hydrothermal conditions

20-Jul-2015 | Author(s): Shigeshi Fuchida, Harue Masuda, Organic Geochemistry, 2015

Publication date: Available online 17 July 2015 Source:Organic Geochemistry Author(s): Shigeshi Fuchida, Harue Masuda Seafloor sediment containing biogenic amino acids was heated with NaCl solutions at 50–200 °C for 240 h to investigate the dissolution process of amino acids and ...


Metal Microporous Aromatic Polymers with Improved Performance for Small Gas Storage

17-Jul-2015 | Xian Fu, Yindong Zhang, Shuai Gu, Yunlong Zhu, Guipeng Yu, Chunyue Pan, Zhonggang Wang, Yuehua Hu, Chemistry - A European Journal, 2015

Abstract A novel metal‐doping strategy was developed for the construction of iron‐decorated microporous aromatic polymers with high small‐gas‐uptake capacities. Cost‐effective ferrocene‐functionalized microporous aromatic polymers (FMAPs) were constructed by a one‐step Friedel–Crafts reaction ...


ChemInform Abstract: Hybrid One‐Dimensional 15‐Crown‐5‐ether‐uranyl‐selenate Polymers in [K@(C10H20O5)] [(UO2)(SeO4)(HSeO4)(H2O)]: Synthesis and Characterization.

16-Jul-2015 | Vladislav V. Gurzhiy, Olga S. Tyumentseva, Sergey V. Krivovichev, Ivan G. Tananaev, ChemInform, 2015

Abstract Yellow‐green prismatic crystals of the title compound are obtained from an aqueous solution containing UO2(NO3)2, K2C2O4, H2SeO4, and 15‐crown‐5 by evaporation at room temperature.


Supramolecular Polymerization Engineered with Molecular Recognition

14-Jul-2015 | Takeharu Haino, The Chemical Record, 2015

Abstract Supramolecular polymeric assemblies represent an emerging, promising class of molecular assemblies with enormous versatility compared with their covalent polymeric counterparts. Although a large number of host–guest motifs have been produced over the history of supramolecular ...


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