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Stabilizing Alginate Confinement and Polymer Coating of CO-Releasing Molecules Supported on Iron Oxide Nanoparticles To Trigger the CO Release by Magnetic Heating

23-Nov-2015 | Hajo Meyer; Felix Winkler; Peter Kunz; Annette M. Schmidt; Alexandra Hamacher; Matthias U. Kassack; Christoph Janiak, Inorganic Chemistry, 2015

Maghemite (Fe2O3) iron oxide nanoparticles (IONPs) were synthesized, modified with covalent surface-bound CO-releasing molecules of a tri(carbonyl)-chlorido-phenylalaninato-ruthenium(II) complex (CORM), and coated with a dextran polymer. The time- and temperature-dependent CO release from this ...


Energies, Vol. 8, Pages 12917-12928: Sodium Tetraethylenepentamine Heptaacetate as Novel Draw Solute for Forward Osmosis—Synthesis, Application and Recovery

16-Nov-2015 | Long, Qing Wu; Wang, Yan, Energies, 2015

Osmotic energy, as a sustainable energy source with little environmental impact, has drawn much attention in both academia and industry in recent years. Osmotically driven membrane processes can harvest the osmotic energy and thus have great potential to produce sustainable clean water or ...


Synthesis and Molecular Structure of a Water-Soluble, Dimeric Tri-Titanium(IV)-Substituted Wells–Dawson Polyoxometalate Containing Two Bridging (C5Me5)Rh2+ Groups

13-Nov-2015 | Yusuke Matsuki; Takahiro Hoshino; Shoko Takaku; Satoshi Matsunaga; Kenji Nomiya, Inorganic Chemistry, 2015

A novel trititanium(IV)-substituted Wells–Dawson polyoxometalate (POM)-based organometallic complex, i.e., a dimeric POM containing two bridging Cp*Rh2+ groups (Cp* = C5Me5) or [{α-P2W15Ti3O60(OH)2}2(Cp*Rh)2]16– (D-1) with Ci symmetry, was synthesized in an analytically pure form by a 1:2 -molar ...


A Nonconventional Model of Protocell-like Vesicles: Anionic Clay Surface-Mediated Formation from a Single-Tailed Amphiphile

10-Nov-2015 | Na Du; Ruiying Song; Haiping Li; Shue Song; Renjie Zhang; Wanguo Hou, Langmuir, 2015

We report a novel model system of precursor cellular membranes, self-assembled from micellar solution of a common anionic single-tailed amphiphile (STA), including sodium dodecyl sulfate (SDS) and sodium dodecylbenzenesulfonate (SDBS). The self-assembly process was mediated with solid surfaces of ...


Impact of solvents and process conditions on the formation of polyethersulfone membranes and its fouling behavior in lake water filtration

05-Nov-2015 | Y. Lukka Thuyavan, N. Anantharaman, G. Arthanareeswaran, A.F. Ismail, Journal of Chemical Technology & Biotechnology, 2015

Abstract Background The existence of natural organic colloids causes the membrane fouling, which decreases the flux rate. Hence, membrane modification and lake water pretreatment were carried out to improve the membrane performance. In this study, important preparation parameters like, ...


Metastable Ni7B3: A New Paramagnetic Boride from Solution Chemistry, Its Crystal Structure and Magnetic Properties

02-Nov-2015 | Kathrin Hofmann; Nalan Kalyon; Christine Kapfenberger; Leo Lamontagne; Salman Zarrini; Robert Berger; Ram Seshadri; ..., Inorganic Chemistry, 2015

We trapped an unknown metastable boride by applying low-temperature solution synthesis. Single-phase nickel boride, Ni7B3, was obtained as bulk samples of microcrystalline powders when annealing the amorphous, nanoscale precipitate that is formed in aqueous solution of nickel chloride upon ...


DiPyMe in SDS Micelles: Artifacts and Their Implications in the Interpretation of Micellar Properties

27-Oct-2015 | Michael Fowler; Victoria Hisko; Jason Henderson; Remi Casier; Lu Li; Janine Lydia Thoma; Jean Duhamel, Langmuir, 2015

This study provides experimental evidence that di(1-pyrenylmethyl) ether or DiPyMe, a well-known fluorescent probe employed to determine the microviscosity of surfactant or polymeric micelles, is being hydrolyzed in the presence of water upon UV irradiation. This effect was established from a ...


IJMS, Vol. 16, Pages 25560-25575: Novel Electrokinetic Microfluidic Detector for Evaluating Effectiveness of Microalgae Disinfection in Ship Ballast Water

26-Oct-2015 | Maw, Myint Myint; Wang, Junsheng ; Li, Fabo ; Jiang, Jinhu ; Song, Younan ; Pan, Xinxiang, International Journal of Molecular Sciences, 2015

Ship ballast water treatment methods face many technical challenges. The effectiveness of every treatment method usually is evaluated by using large scale equipment and a large volume of samples, which involves time-consuming, laborious, and complex operations. This paper reports the development ...


Phase Behavior of Biocompatible Microemulsions Formed by Sucrose Stearate in the Presence of Sodium Deoxycholate

26-Oct-2015 | Jingjing Liang; Zhongni Wang, Journal of Chemical & Engineering Data, 2015

Biocompatible microemulsion has received increased interest among other self-assembly systems. On the basis of the phase behavior of sucrose stearate (S1570)/isopropyl alcohol/isoamyl acetate/water with α = 0.5 was investigated at 313 K, and found that emulsification occurs in this system. When ...


Hollow PUA/PSS/Au microcapsules with interdependent near‐infrared/pH/temperature multiresponsiveness

23-Oct-2015 | Shuhan Xu, Jun Shi, Liu Yang, Qiong Wu, Shaokui Cao, Journal of Applied Polymer Science, 2015

ABSTRACT In this work, smart hollow microcapsules made of thermal‐/pH‐dual sensitive aliphatic poly(urethane‐amine) (PUA), sodium poly(styrenesulfonate) (PSS), and Au nanoparticles (AuNPs) for interdependent multi‐responsive drug delivery have been constructed by layer‐by‐layer (LbL) ...


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