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2,548 Newest Publications about the topic solution

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Paddlewheel‐Type Dirhodium Tetrapivalate Based Coordination Polymer: Synthesis, Characterization, and Self‐Assembly and Disassembly Transformation Properties

25-Apr-2016 | Yusuke Kataoka, Natsumi Yano, Takashi Shimodaira, Yin‐Nan Yan, Mikio Yamasaki, Hidekazu Tanaka, Kohji Omata, Tatsuya ..., European Journal of Inorganic Chemistry, 2016

Abstract An extended one‐dimensional chain‐type coordination polymer, [Rh2(piv)4(tpy)]n (1; piv = pivalate, tpy = 2,2′:6′,2″‐terpyridine), has been synthesized and characterized by single‐crystal and powder X‐ray diffraction analyses, elemental analysis, IR spectrosopy, thermogravimetric ...


Role of the dithiolate backbone on the passivation of p-GaAs(111)B surface

25-Apr-2016 | Author(s): Loredana Preda, Mihai Anastasescu, Gianina Dobrescu, Catalin Negrila, Valentina Lazarescu, Journal of Electroanalytical Chemistry, 2016

Publication date: 15 June 2016 Source:Journal of Electroanalytical Chemistry, Volume 771 Author(s): Loredana Preda, Mihai Anastasescu, Gianina Dobrescu, Catalin Negrila, Valentina Lazarescu Effects of the self-assembled layers of biphenyl 4,4′ –dithiol (BPDT) and 1,8 ...


Electronic Structures and Chiroptical Properties of Post‐functionalized Helicene Quinones

23-Apr-2016 | David Schweinfurth, Marcella Mazzolini, Dmytro Neshchadin, Carolin Hoyer, Roman Geier, Karl Gatterer, Nils Trapp, Ge ..., Chemistry - A European Journal, 2016

Abstract The synthesis of redox‐active p‐ and o‐quinones 2‐phenylamino‐4‐phenylimino[6]helicene‐1‐one 1, 2‐phenylamino[6]‐helicene‐1,4‐dione 2, and 4‐phenyl[6]helicene‐1,2‐dione 3 in their enantiopure forms by post‐functionalization of (P)‐ and (M)‐1,2‐dimethoxy[6]helicene is presented. ...


Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-ray Scattering and EXAFS Spectroscopy

22-Apr-2016 | Ke R. Yang; Adam J. Matula; Gihan Kwon; Jiyun Hong; Stafford W. Sheehan; Julianne M. Thomsen; Gary W. Brudvig; Rober ..., Journal of the American Chemical Society, 2016

The solution structures of highly active Ir water-oxidation catalysts are elucidated by combining density functional theory, high-energy X-ray scattering (HEXS), and extended X-ray absorption fine structure (EXAFS) spectroscopy. We find that the catalysts are Ir dimers with mono-μ-O cores and ...


Long-Range Vibrational Dynamics Are Directed by Watson–Crick Base Pairing in Duplex DNA

22-Apr-2016 | Gordon Hithell; Daniel J. Shaw; Paul M. Donaldson; Gregory M. Greetham; Michael Towrie; Glenn A. Burley; Anthony W. ..., Journal of Physical Chemistry B, 2016

Ultrafast two-dimensional infrared (2D-IR) spectroscopy of a 15-mer A–T DNA duplex in solution has revealed structure-dependent vibrational coupling and energy transfer processes linking bases with the sugar–phosphate backbone. Duplex melting induces significant changes in the positions of ...


XANES Reveals the Flexible Nature of Hydrated Strontium in Aqueous Solution

22-Apr-2016 | Paola D’Angelo; Valentina Migliorati; Francesco Sessa; Giordano Mancini; Ingmar Persson, Journal of Physical Chemistry B, 2016

X-ray absorption near-edge structure (XANES) spectroscopy has been used to determine the structure of the hydrated strontium in aqueous solution. The XANES analysis has been carried out using solid [Sr(H2O)8](OH)2 as reference model. Classical and Car–Parrinello molecular dynamics (MD) ...


η4‐HBCC‐σ,π‐Borataallyl Complexes of Ruthenium Comprising an Agostic Interaction

21-Apr-2016 | Koushik Saha, Benson Joseph, Rongala Ramalakshmi, R. S. Anju, Babu Varghese, Sundargopal Ghosh, Chemistry - A European Journal, 2016

Abstract Thermolysis of [Cp*Ru(PPh2(CH2)PPh2)BH2(L2)] 1 (Cp*=η5‐C5Me5; L=C7H4NS2), with terminal alkynes led to the formation of η4‐σ,π‐borataallyl complexes [Cp*Ru(μ‐H)B{R‐C=CH2}(L)2] (2 a–c) and η2‐vinylborane complexes [Cp*Ru(R‐C=CH2)BH(L)2] (3 a–c) (2 a, 3 a: R=Ph; 2 b, 3 b: R=COOCH3; 2 c, ...


The effect of disulfide bonds on protein folding, unfolding, and misfolding investigated by FT–Raman spectroscopy

21-Apr-2016 | Chih‐Hsien Wang, Chia‐Chi Huang, Long‐Liu Lin, Wenlung Chen, Journal of Raman Spectroscopy, 2016

Disulfide bond is relevant to many protein folding/unfolding functions and conformational diseases. To elucidate the effects of disulfide bonds on protein folding, unfolding, and misfolding, we performed Fourier transform–Raman measurements on serial chemical‐induced denaturations of bovine ...


Polyvinylferrocene-Based Amphiphilic Block Copolymers Featuring Functional Junction Points for Cross-Linked Micelles

21-Apr-2016 | Jan Morsbach; Johannes Elbert; Christian Rüttiger; Svenja Winzen; Holger Frey; Markus Gallei, Macromolecules, 2016

The synthesis of high-molecular-weight, well-defined poly(vinylferrocene)-block-poly(ethylene glycol) (PVFc-b-PEG) diblock copolymers (Mn = 13 000–44 000 g mol–1; Đ = 1.29–1.34) with precisely one allyl group at the junction point is introduced. Allyl glycidyl ether (AGE) was used to ...


Electrografting of 3-Aminopropyltriethoxysilane on a Glassy Carbon Electrode for the Improved Adhesion of Vertically Oriented Mesoporous Silica Thin Films

21-Apr-2016 | Tauqir Nasir; Lin Zhang; Neus Vilà; Grégoire Herzog; Alain Walcarius, Langmuir, 2016

Vertically oriented mesoporous silica has proven to be of interest for applications in a variety of fields (e.g., electroanalysis, energy, and nanotechnology). Although glassy carbon is widely used as an electrode material, the adherence of silica deposits is rather poor, causing mechanical ...


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