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2,548 Newest Publications about the topic solution

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Paddlewheel‐Type Dirhodium Tetrapivalate Based Coordination Polymer: Synthesis, Characterization, and Self‐Assembly and Disassembly Transformation Properties

25-Apr-2016 | Yusuke Kataoka, Natsumi Yano, Takashi Shimodaira, Yin‐Nan Yan, Mikio Yamasaki, Hidekazu Tanaka, Kohji Omata, Tatsuya ..., European Journal of Inorganic Chemistry, 2016

Abstract An extended one‐dimensional chain‐type coordination polymer, [Rh2(piv)4(tpy)]n (1; piv = pivalate, tpy = 2,2′:6′,2″‐terpyridine), has been synthesized and characterized by single‐crystal and powder X‐ray diffraction analyses, elemental analysis, IR spectrosopy, thermogravimetric ...

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Role of the dithiolate backbone on the passivation of p-GaAs(111)B surface

25-Apr-2016 | Author(s): Loredana Preda, Mihai Anastasescu, Gianina Dobrescu, Catalin Negrila, Valentina Lazarescu, Journal of Electroanalytical Chemistry, 2016

Publication date: 15 June 2016 Source:Journal of Electroanalytical Chemistry, Volume 771 Author(s): Loredana Preda, Mihai Anastasescu, Gianina Dobrescu, Catalin Negrila, Valentina Lazarescu Effects of the self-assembled layers of biphenyl 4,4′ –dithiol (BPDT) and 1,8 ...

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Electronic Structures and Chiroptical Properties of Post‐functionalized Helicene Quinones

23-Apr-2016 | David Schweinfurth, Marcella Mazzolini, Dmytro Neshchadin, Carolin Hoyer, Roman Geier, Karl Gatterer, Nils Trapp, Ge ..., Chemistry - A European Journal, 2016

Abstract The synthesis of redox‐active p‐ and o‐quinones 2‐phenylamino‐4‐phenylimino[6]helicene‐1‐one 1, 2‐phenylamino[6]‐helicene‐1,4‐dione 2, and 4‐phenyl[6]helicene‐1,2‐dione 3 in their enantiopure forms by post‐functionalization of (P)‐ and (M)‐1,2‐dimethoxy[6]helicene is presented. ...

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Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-ray Scattering and EXAFS Spectroscopy

22-Apr-2016 | Ke R. Yang; Adam J. Matula; Gihan Kwon; Jiyun Hong; Stafford W. Sheehan; Julianne M. Thomsen; Gary W. Brudvig; Rober ..., Journal of the American Chemical Society, 2016

The solution structures of highly active Ir water-oxidation catalysts are elucidated by combining density functional theory, high-energy X-ray scattering (HEXS), and extended X-ray absorption fine structure (EXAFS) spectroscopy. We find that the catalysts are Ir dimers with mono-μ-O cores and ...

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Long-Range Vibrational Dynamics Are Directed by Watson–Crick Base Pairing in Duplex DNA

22-Apr-2016 | Gordon Hithell; Daniel J. Shaw; Paul M. Donaldson; Gregory M. Greetham; Michael Towrie; Glenn A. Burley; Anthony W. ..., Journal of Physical Chemistry B, 2016

Ultrafast two-dimensional infrared (2D-IR) spectroscopy of a 15-mer A–T DNA duplex in solution has revealed structure-dependent vibrational coupling and energy transfer processes linking bases with the sugar–phosphate backbone. Duplex melting induces significant changes in the positions of ...

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XANES Reveals the Flexible Nature of Hydrated Strontium in Aqueous Solution

22-Apr-2016 | Paola D’Angelo; Valentina Migliorati; Francesco Sessa; Giordano Mancini; Ingmar Persson, Journal of Physical Chemistry B, 2016

X-ray absorption near-edge structure (XANES) spectroscopy has been used to determine the structure of the hydrated strontium in aqueous solution. The XANES analysis has been carried out using solid [Sr(H2O)8](OH)2 as reference model. Classical and Car–Parrinello molecular dynamics (MD) ...

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η4‐HBCC‐σ,π‐Borataallyl Complexes of Ruthenium Comprising an Agostic Interaction

21-Apr-2016 | Koushik Saha, Benson Joseph, Rongala Ramalakshmi, R. S. Anju, Babu Varghese, Sundargopal Ghosh, Chemistry - A European Journal, 2016

Abstract Thermolysis of [Cp*Ru(PPh2(CH2)PPh2)BH2(L2)] 1 (Cp*=η5‐C5Me5; L=C7H4NS2), with terminal alkynes led to the formation of η4‐σ,π‐borataallyl complexes [Cp*Ru(μ‐H)B{R‐C=CH2}(L)2] (2 a–c) and η2‐vinylborane complexes [Cp*Ru(R‐C=CH2)BH(L)2] (3 a–c) (2 a, 3 a: R=Ph; 2 b, 3 b: R=COOCH3; 2 c, ...

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The effect of disulfide bonds on protein folding, unfolding, and misfolding investigated by FT–Raman spectroscopy

21-Apr-2016 | Chih‐Hsien Wang, Chia‐Chi Huang, Long‐Liu Lin, Wenlung Chen, Journal of Raman Spectroscopy, 2016

Disulfide bond is relevant to many protein folding/unfolding functions and conformational diseases. To elucidate the effects of disulfide bonds on protein folding, unfolding, and misfolding, we performed Fourier transform–Raman measurements on serial chemical‐induced denaturations of bovine ...

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Polyvinylferrocene-Based Amphiphilic Block Copolymers Featuring Functional Junction Points for Cross-Linked Micelles

21-Apr-2016 | Jan Morsbach; Johannes Elbert; Christian Rüttiger; Svenja Winzen; Holger Frey; Markus Gallei, Macromolecules, 2016

The synthesis of high-molecular-weight, well-defined poly(vinylferrocene)-block-poly(ethylene glycol) (PVFc-b-PEG) diblock copolymers (Mn = 13 000–44 000 g mol–1; Đ = 1.29–1.34) with precisely one allyl group at the junction point is introduced. Allyl glycidyl ether (AGE) was used to ...

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Electrografting of 3-Aminopropyltriethoxysilane on a Glassy Carbon Electrode for the Improved Adhesion of Vertically Oriented Mesoporous Silica Thin Films

21-Apr-2016 | Tauqir Nasir; Lin Zhang; Neus Vilà; Grégoire Herzog; Alain Walcarius, Langmuir, 2016

Vertically oriented mesoporous silica has proven to be of interest for applications in a variety of fields (e.g., electroanalysis, energy, and nanotechnology). Although glassy carbon is widely used as an electrode material, the adherence of silica deposits is rather poor, causing mechanical ...

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