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Dual-responsive vesicles formed by an amphiphile appended two tetrathiafulvalene units in aqueous solution

25-Nov-2015 | Li-Zhu Wu; Xiao-Jun Wang; Ling-Bao Xing; Bin Chen; Ying Quan; Chen Ho Tung, Organic & Biomolecular Chemistry, 2015

The first example of tetrathiafulvalene (TTF)-based vesicle fabricated in water solution with 1 vol% tetrahydrofuran that could be prevented by chemical oxidant Fe(ClO4)3 or electron-deficient cyclobis(paraquat-p-phenylene) tetracation cyclophane (CBPQT4+) is described.


Accordion-like swelling of layered perovskite crystals via massive permeation of aqueous solutions into 2D oxide galleries

25-Nov-2015 | Yeji Song; Nobuo Iyi; Tatsumasa Hoshide; Tadashi C. Ozawa; Yasuo Ebina; Renzhi Ma; Nobuyoshi Miyamoto; Takayoshi Sasaki, Chemical Communication, 2015

Platelet crystals of a layered perovskite showed massive accordion-like swelling in a tetrabutylammonium hydroxide solution. The permeation of the solution induced the huge expansion of the interlayer spacing as well as the crystal thickness up to 50-fold, leading to a very high water content of


Black Phosphorus (BP) Nanodots for Potential Biomedical Applications

20-Nov-2015 | Hyun Uk Lee, So Young Park, Soon Chang Lee, Saehae Choi, Soonjoo Seo, Hyeran Kim, Jonghan Won, Kyuseok Choi, Kyoung ..., Small, 2015

Recently, the appeal of 2D black phosphorus (BP) has been rising due to its unique optical and electronic properties with a tunable band gap (≈0.3–1.5 eV). While numerous research efforts have recently been devoted to nano‐ and optoelectronic applications of BP, no attention has been paid to ...


The Control of Conjugation Lengths and Steric Hindrance to Modulate Aggregation‐Induced Emission with High Electroluminescence Properties and Interesting Optical Properties

20-Nov-2015 | Miao‐Miao Xue, Yue‐Min Xie, Lin‐Song Cui, Xiang‐Yang Liu, Xiao‐Dong Yuan, Yong‐Xi Li, Zuo‐Quan Jiang, Liang‐Sheng Liao, Chemistry - A European Journal, 2015

Abstract A series of novel AIE‐active (aggregation‐induced emission) molecules, named SAF‐2‐TriPE, SAF‐3‐TriPE, and SAF‐4‐TriPE, were designed and synthesized through facile reaction procedures. We found that incorporation of the spiro‐acridine‐fluorene (SAF) group, which is famous for its ...


Removal of Cr(VI) from aqueous solution using amino‐modified Fe3O4–SiO2–chitosan magnetic microspheres with high acid resistance and adsorption capacity

20-Nov-2015 | Xitong Sun, Liangrong Yang, Tingting Dong, Zhini Liu, Huizhou Liu, Journal of Applied Polymer Science, 2015

ABSTRACT A novel, bioadsorbent material of polyethylenimine‐modified magnetic chitosan microspheres enwrapping magnetic silica nanoparticles (Fe3O4–SiO2–CTS‐PEI) was prepared under relatively mild conditions. The characterization results indicated that the adsorbent exhibited high acid ...


Impact of Water-Depletion Layer on Transport in Hydrophobic Nanochannels

20-Nov-2015 | Yuhui He; Makusu Tsutsui; Xiang Shui Miao; Masateru Taniguchi, Analytical Chemistry, 2015

Recent experiments showed that by fabricating nanofluidic channels with hydrophobic materials, the measured amplitudes of both electroosmotic flow (EOF) and ionic current deviated significantly from the conventional electrokinetic modeling indication. Among these unexpected observations, the ...


Development of a Smart, Anti‐Water Polyurethane Polymer Hair Coating for Style Setting

19-Nov-2015 | Liu Yan, Liu Yijun, Jinlian Hu, Ji FengLong, Lv Jing, Chen Shao Jun, Zhu Yong, International Journal of Cosmetic Science, 2015

Abstract Objective The goal of this work was to develop a novel polyurethane polymer coating for the surface of the hair that could be used for style setting via the shape memory effect. The features of the films are in accordance with conventional hair styling methods used in the ...


Gas phase silanization for silicon nanowire sensors and other lab‐on‐a‐chip systems

19-Nov-2015 | Annina M. Steinbach, Tanja Sandner, Boris Mizaikoff, Steffen Strehle, physica status solidi (c), 2015

Abstract Designing a microfabrication process for lab‐on‐a‐chip systems can at times be challenging, and the need to integrate a chemical surface modification reaction into this process can limit the options. Therefore, a robust set‐up and protocol for the gas phase modification has been ...


Energies, Vol. 8, Pages 13137-13161: Multi-Objective Optimization Design for Indirect Forced-Circulation Solar Water Heating System Using NSGA-II

19-Nov-2015 | Ko, Myeong Jin, Energies, 2015

In this study, the multi-objective optimization of an indirect forced-circulation solar water heating (SWH) system was performed to obtain the optimal configuration that minimized the life cycle cost (LCC) and maximized the life cycle net energy saving (LCES). An elitist non-dominated sorting ...


Colorimetric Humidity and Solvent Recognition Based on a Cation-Exchange Clay Mineral Incorporating Nickel(II)–Chelate Complexes

19-Nov-2015 | Hitoshi Hosokawa; Tomoyuki Mochida, Langmuir, 2015

Solvatochromic nickel(II) complexes with diketonato and diamine ligands were incorporated into a saponite clay by ion exchange, and their colorimetric humidity- and solvent-recognition properties were investigated. These powders exhibit color change from red to blue-green depending on humidity, ...


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