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Selective turn-off phosphorescent and colorimetric detection of mercury(II) in water by half-lantern platinum(II) complexes

26-Mar-2015 | Violeta Sicilia; Pilar Borja; Miguel Baya; José M. Casas, Dalton Transactions, 2015

The platinum(ii) half-lantern dinuclear complexes [{Pt(bzq)(μ-C7H4NS2-κN,S)}2] (A) and [{Pt(bzq)(μ-C7H4NOS-κN,S)}2] (B) [bzq = benzo[h]quinolinate, C7H4NS2 = 2-mercaptobenzothiazolate, C7H4NOS = 2-mercaptobenzoxazolate] in solution of DMSO–H2O undergo a dramatic color change from yellowish-orange ...

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A dual-responsive supra-amphiphile based on a water-soluble pillar[7]arene and a naphthalene diimide-containing guest

24-Mar-2015 | Guocan Yu; Li Shao; Jiong Zhou; Bin Hua, Chemical Communication, 2015

A dual-responsive supra-amphiphile was firstly constructed based on a water-soluble pillar[7]arene and a naphthalene diimide-containing guest with a long alkyl chain and a trimethylammonium group. The morphologies of the self-assembly formed from this supra-amphiphile could be adjusted by ...

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Dye biosorption from water employing chemically modified calabrian pine cone shell as an effective biosorbent

22-Mar-2015 | Fatih Deniz, Environmental Progress, 2015

The feasibility of base (0.1 M NaOH) treated cone shell of Calabrian pine as an effective and inexpensive biosorbent was examined for removal of C.I. Basic Red 46 as a model azo dye from aqueous solution. Biosorption conditions selected for this study were optimized using Taguchi experimental ...

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p‐Si/SnO2/Fe2O3 Core/Shell/Shell Nanowire Photocathodes for Neutral pH Water Splitting

21-Mar-2015 | Alireza Kargar, Sung Joo Kim, Paniz Allameh, Chulmin Choi, Namseok Park, Huisu Jeong, Yusin Pak, Gun Young Jung, Xia ..., Advanced Functional Materials, 2015

Silicon is one of the promising materials for solar water splitting and hydrogen production; however, it suffers from two key factors, including the large external potential required to drive water splitting reactions at its surface and its instability in the electrolyte. In this study, a ...

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Physiochemical Properties, Microstructure, and Probiotic Survivability of Nonfat Goats’ Milk Yogurt Using Heat‐Treated Whey Protein Concentrate as Fat Replacer

21-Mar-2015 | Tiehua Zhang, James McCarthy, Guorong Wang, Yanyan Liu, Mingruo Guo, Journal of Food Science, 2015

Abstract There is a market demand for nonfat fermented goats’ milk products. A nonfat goats’ milk yogurt containing probiotics (Lactobacillus acidophilus, and Bifidobacterium spp.) was developed using heat‐treated whey protein concentrate (HWPC) as a fat replacer and pectin as a thickening ...

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Evidence of Amine–CO2 Interactions in Two Pillared‐Layer MOFs Probed by X‐Ray Crystallography

20-Mar-2015 | Xiao‐Li Hu, Qi‐Han Gong, Rong‐Lin Zhong, Xin‐Long Wang, Chao Qin, Hao Wang, Jing Li, Kui‐Zhan Shao, Zhong‐Min Su, Chemistry - A European Journal, 2015

Abstract Two pillared‐layer metal–organic frameworks (MOFs; PMOF‐55 and NH2‐PMOF‐55) based on 1,2,4‐triazole and terephthalic acid (bdc)/NH2‐bdc ligands were assembled and display framework stabilities, to a certain degree, in both acid/alkaline solutions and toward water. They exhibit high ...

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Intumescent Flame-Retardant and Self-Healing Superhydrophobic Coatings on Cotton Fabric

20-Mar-2015 | Shanshan Chen; Xiang Li; Yang Li; Junqi Sun, ACS Nano, 2015

Flame-retardant and self-healing superhydrophobic coatings are fabricated on cotton fabric by a convenient solution-dipping method, which involves the sequential deposition of a trilayer of branched poly(ethylenimine) (bPEI), ammonium polyphosphate (APP), and fluorinated-decyl polyhedral ...

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Low‐Temperature, Nontoxic Water‐Induced Metal‐Oxide Thin Films and Their Application in Thin‐Film Transistors

19-Mar-2015 | Guoxia Liu, Ao Liu, Huihui Zhu, Byoungchul Shin, Elvira Fortunato, Rodrigo Martins, Yiqian Wang, Fukai Shan, Advanced Functional Materials, 2015

Here, a simple, nontoxic, and inexpensive “water‐inducement” technique for the fabrication of oxide thin films at low annealing temperatures is reported. For water‐induced (WI) precursor solution, the solvent is composed of water without additional organic additives and catalysts. The ...

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Highly Efficient Forward Osmosis Based on Porous Membranes—Applications and Implications

19-Mar-2015 | Saren Qi; Ye Li; Yang Zhao; Weiyi Li; Chuyang Y. Tang, Environmental Science & Technology, 2015

For the first time, forward osmosis (FO) was performed using a porous membrane with an ultrafiltration (UF)-like rejection layer and its feasibility for high performance FO filtration was demonstrated. Compared to traditional FO membranes with dense rejection layers, the UF-like FO membrane was 2 ...

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Theoretical Study on Structures and Bond Properties of NpO2m+ Ions and NpO2(H2O)nm+ (m = 1–2, n = 1–6) Complexes in the Gas Phase and Aqueous Solution

19-Mar-2015 | Yao-Peng Yin; Chen-Zhong Dong; Xiao-Bin Ding, Journal of Physical Chemistry A, 2015

The equilibrium structures, vibrational frequencies, and bond characteristics of NpO2m+ ions and NpO2(H2O)nm+ (m = 1–2, n = 1–6) complexes have been studied by carrying out ab initio calculations in the gas phase and aqueous solution. The geometries have been obtained at the B3LYP level with the ...

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