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Cu7S4 Nanosuperlattices with Greatly Enhanced Photothermal Efficiency

15-May-2015 | Jiabin Cui, Rui Jiang, Suying Xu, Gaofei Hu, Leyu Wang, Small, 2015

According to the simulation, the self‐assembly of Cu7S4 nanocrystals would enhance the photothermal conversion efficiency (PCE) because of the localized surface plasmon resonance effects, which is highly desirable for photothermal therapy (PTT). A new strategy to synthesize Cu7S4 ...


Effects of nano‐tio2 on the performance of high‐amylose starch based antibacterial films

14-May-2015 | Chao Liu, Hanguo Xiong, Xing Chen, Shun Lin, Yanhua Tu, Journal of Applied Polymer Science, 2015

ABSTRACT The purpose of this article is to investigate the effects of nano‐tianium dioxide (nano‐TiO2) on the high‐amylose starch/polyvingl alcohol (PVA) blend films prepared by a solution casting method. The results show that at the concentration of 0.6% of nano‐TiO2, the film demonstrated ...


A biomimetic surface treatment to obtain durable omniphobic textiles

14-May-2015 | Carmela De Marco, Valeria Oldani, Claudia Letizia Bianchi, Marinella Levi, Stefano Turri, Journal of Applied Polymer Science, 2015

ABSTRACT A bio‐inspired surface treatment to make fabrics omniphobic is reported, exploiting the ability of dopamine – a widespread naturally occurring biological neurotransmitter – to give substrate adhesion and surface immobilization. Standard polyester and polyacrylonitrile fabrics, which ...


Salting‐Out of Acetone, 1‐Butanol, and Ethanol from Dilute Aqueous Solutions

14-May-2015 | Shaoqu Xie, Conghua Yi, Xueqing Qiu, AIChE Journal, 2015

ABSTRACT The salting‐out phase equilibria for acetone, 1‐butanol, and ethanol (ABE) from dilute aqueous solutions by using potassium carbonate (K2CO3) and dipotassium hydrogen phosphate trihydrate (K2HPO4·3H2O) as outstanding salting‐out agents were investigated. Increasing the salt ...


Materials, Vol. 8, Pages 2635-2649: Electrochemical Investigation of the Corrosion of Different Microstructural Phases of X65 Pipeline Steel under Saturated Carbon Dioxide Conditions

14-May-2015 | Yang, Yuanfeng ; Akid, Robert, Materials, 2015

The aim of this research was to investigate the influence of metallurgy on the corrosion behaviour of separate weld zone (WZ) and parent plate (PP) regions of X65 pipeline steel in a solution of deionised water saturated with CO2, at two different temperatures (55 °C and 80 °C) and at initial ...


Theoretical Study of Decomposition of Methanediol in Aqueous Solution

14-May-2015 | Satoshi Inaba, Journal of Physical Chemistry A, 2015

Methanediol is a product of the hydration of formaldehyde and is more abundant than formaldehyde in aqueous solution. We carried out a number of quantum chemical simulations to study the decomposition of methanediol in aqueous solution. The decomposition of a methanediol proceeds by transferring ...


Preparation of upper critical solution temperature (UCST) responsive diblock copolymers bearing pendant ureido groups and their micelle formation behavior in water

14-May-2015 | Ami Fujihara; Naohiko Shimada; Atsushi Maruyama; Kazuhiko Ishihara; Keita Nakai; Shinichi Yusa, Soft Matter, 2015

Poly(2-ureidoethyl methacrylate) (PUEM) was prepared via reversible addition-fragmentation chain transfer (RAFT) controlled radical polymerization and post-modification reaction. PUEM shows upper critical solution temperature (UCST) behavior in aqueous solution. Although PUEM can dissolve in ...


Catalytic Allylic Arylation of Cinnamyl Carbonates over Palladium Nanoparticles Supported on a Thermoresponsive Polymer in Water

14-May-2015 | Yongwoo Lee; Saira Shabbir; Sinyoung Lee; Hyunsoek Ahn; Hakjune Rhee, Green Chemistry, 2015

Poly(NIPAM-co-4-VP) undergoes phase transition at low critical solution temperature with a change from hydrophilic to hydrophobic core in hydrophilic solvent. Palladium nanoparticles supported on such thermoresponsive polymer support were demonstrated to catalyze the Tsuji-Trost reaction for the ...


Solubility of 3,7-Dinitro-1,3,5,7-tetraazabicyclo [3.3.1] Nonane in Ethanenitrile, Methanol, 1,1-Dichloroethane, Dimethyl Sulfoxide, Acetone, and Mixed Solvents

13-May-2015 | Min Xue; Siyu Wu; Wenjin Liu; Qiao Zhu; Zihui Meng; Zhihui Lin, Journal of Chemical & Engineering Data, 2015

The solubility of 3,7-dinitro-1,3,5,7-tetraazabicyclo [3.3.1] nonane (DPT) was measured in ethanenitrile, methanol, 1,1-dichloroethane, dimethyl sulfoxide (DMSO), acetone, ethyl acetate, ethyl acetate and methanol mixture, and acetonitrile and water mixture from 288.15 K to 308.15 K. In this ...


IJMS, Vol. 16, Pages 10767-10796: Theoretical in-Solution Conformational/Tautomeric Analyses for Chain Systems with Conjugated Double Bonds Involving Nitrogen(s)

13-May-2015 | Nagy, Peter I., International Journal of Molecular Sciences, 2015

Conformational/tautomeric transformations for X=CH–CH=Y structures (X = CH2, O, NH and Y = NH) have been studied in the gas phase, in dichloromethane and in aqueous solutions. The paper is a continuation of a former study where s-cis/s-trans conformational equilibria were predicted for ...


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