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Self-assembled Metallogels Formed From N, N', N''-tris(4-pyridyl)-trimesic amide in Aqueous Solution Induced by Fe(III)/Fe(II) Ions

08-Oct-2015 | Jin-Lian Zhong; Xin-Jian Jia; Hui-jin Liu; xuzhong luo; San-Guo Hong; Ning Zhang; Jianbin Huang, Soft Matter, 2015

In this work, we report self-assembled metallogels formed from a ligand of trimesic amide, N,N′,N″-tris(4-pyridyl)trimesic amide (TPTA), induced by Fe(III)/Fe(II) ions. TPTA is difficult to dissolve in water even in the presence of some metal ions such as Cu2+, Co2+, Ni2+, K+, Na+ and Mg2+ under ...


Simple hydrated salts in methanolic and aqueous solutions – acoustic and spectroscopic studies

04-Oct-2015 | Author(s): Andrzej Burakowski, Jacek Gliński, Joanna Wachał, Małgorzata Guzik, Chemical Physics, 2015

Publication date: Available online 30 September 2015 Source:Chemical Physics Author(s): Andrzej Burakowski, Jacek Gliński, Joanna Wachał, Małgorzata Guzik Hydrated salts, MgCl2 .6H2O, CuCl2 .2H2O and EuCl3 .6H2O when dissolved in methanol, conserve their original coordination ...


Genipin-cross-linked silk sericin/poly(N-isopropylacrylamide) IPN hydrogels: Color reaction between silk sericin and genipin, pore shape and thermo-responsibility

04-Oct-2015 | Author(s): Qingsong Zhang, Xiaozhao Wang, Qifeng Mu, Pengfei Liu, Shujun Jia, Li Chen, Xiaoyong Zhang, ..., Materials Chemistry and Physics, 2015

Publication date: Available online 1 October 2015 Source:Materials Chemistry and Physics Author(s): Qingsong Zhang, Xiaozhao Wang, Qifeng Mu, Pengfei Liu, Shujun Jia, Li Chen, Xiaoyong Zhang, Ke Wang, Yen Wei To investigate the color reactions between naturally ...


Thin Films: Long Range Self‐Assembly of Polythiophene Breath Figures: Optical and Morphological Characterization (Adv. Funct. Mater. 37/2015)

02-Oct-2015 | Prahlad K. Routh, Dmytro Nykypanchuk, T. A. Venkatesh, Mircea Cotlet, Advanced Functional Materials, 2015

Large area semitransparent thin films with highly ordered microporous structures are formed from a commercial conjugated polymer by the use of the breath figure technique, as shown by T. A. Venkatesh, M. Cotlet, and co‐workers on page 5902. In this self‐assembly method, humid air flow ...


Controllable Perovskite Crystallization by Water Additive for High‐Performance Solar Cells

02-Oct-2015 | Xiu Gong, Meng Li, Xiao‐Bo Shi, Heng Ma, Zhao‐Kui Wang, Liang‐Sheng Liao, Advanced Functional Materials, 2015

A key issue for perovskite solar cells is the stability of perovskite materials due to moisture effects under ambient conditions, although their efficiency is improved constantly. Herein, an improved CH3NH3PbI3−xClx perovskite quality is demonstrated with good crystallization and stability by ...


Synthesis of a cellulose‐based hydrogel network: Characterization and study of urea fertilizer slow release

02-Oct-2015 | Shahin Mohammadi‐Khoo, Peyman Najafi Moghadam, Amir Reza Fareghi, Nasim Movagharnezhad, Journal of Applied Polymer Science, 2015

ABSTRACT In the present study, we synthesized a low‐cost biodegradable hydrogel based on cellulose in order to perform controlled release of fertilizer. For this purpose, the cellulose was modified and crosslinked with urea. Then the prepared hydrogel underwent loading with the fertilizer in ...


Diamond‐coated three‐dimensional GaN micromembranes: Effect of nucleation and deposition techniques

02-Oct-2015 | Tibor Izak, Gabriel Vanko, Oleg Babchenko, Štěpán Potocký, Marian Marton, Marian Vojs, Pavlina Choleva, Alexander Kromka, physica status solidi (b), 2015

In this work, we present technological issues in the deposition of polycrystalline diamond films as a backside heat spreader for GaN membranes. We compared three nucleation techniques, including standard ultrasonic seeding by diamond powder (DP) in deionized water, drop‐off technique with DP in ...


Efficient Light‐Driven Water Oxidation Catalysis by Dinuclear Ruthenium Complexes

01-Oct-2015 | Serena Berardi, Laia Francàs, Sven Neudeck, Somnath Maji, Jordi Benet‐Buchholz, Franc Meyer, Antoni Llobet, ChemSusChem, 2015

Abstract Mastering the light‐induced four‐electron oxidation of water to molecular oxygen is a key step towards the achievement of overall water splitting to produce alternative solar fuels. In this work, we report two rugged molecular pyrazolate‐based diruthenium complexes that efficiently ...


Surfactin at the Water/Air Interface and in Solution

01-Oct-2015 | Javier Iglesias-Fernández; Leonardo Darré; Axel Kohlmeyer; Robert K. Thomas; Hsin-Hui Shen; Carmen Domene, Langmuir, 2015

The lipopeptide surfactin produced by certain strains of Bacillus subtillis is a potent biosurfactant with high amphiphilicity and a strong tendency for self-aggregation. Surfactin possesses a number of valuable biological properties such as antiviral, antibacterial, antifungal, and hemolytic ...


Surface Electrostatic Potential and Water Orientation in the presence of Sodium Octanoate Dilute Monolayers Studied by Means of Molecular Dynamics Simulations

01-Oct-2015 | Kalil Bernardino; André F. de Moura, Langmuir, 2015

A series of atomistic molecular dynamics simulations were performed in the present investigation to assess the spontaneous formation of surfactant monolayers of sodium octanoate at the water–vacuum interface. The surfactant surface coverage increased until a saturation threshold was achieved, ...


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