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Synthesis and Visible-Light Photochromism of a New Composite Based on Polymolybdate Enclosed in Magadiite

13-06-2013 | Yufeng Chen; Gensheng Yu; Fei Li; Michael Severance, Inorganic Chemistry, 2013

A new composite based on polymolybdate incorporated in layered magadiite has been synthesized via a exfoliation/self-assembly process. Various techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy coupled with energy-dispersive ...

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Effect of Processing Parameters on Cerium Oxide Coating Deposition in Solution Precursor Plasma Spray

12-06-2013 | Virendra Singh, Robert Draper, Sudipta Seal, Journal of the American Ceramic Society, 2013

Solution precursor plasma spray was used to deposit cerium oxide coating. This study is to understand the coating deposition mechanism in solution precursor plasma spray for cerium oxide using a cerium nitrate liquid precursor. This study includes the effect of various processing parameters ...

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A highly luminescent terbium-organic framework for reversible detection of mercury ions in aqueous solution

12-06-2013 | Hong-Ming Wang; Yang-Yi Yang; Cheng-Hui Zeng; Tian-Shu Chu; Yi-Min Zhu; Ng Seik Weng, Photochemical & Photobiological Sciences, 2013

A new organic-lanthanide framework [TbL1.5(H2O)2]•H2O (1) [H2L = 5-(3΄-carboxylphenyl) nicotinic acid] was synthesized. Its structure was determined by single crystal X-ray diffraction, and the complex was characterized by PXRD, FT-IR, fluorescence and TGA, which features 3D framework with 1D ...

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Facile one-pot synthesis of lepidocrocite ([gamma]-FeOOH) nanoflakes for water treatment

12-06-2013 | Yong Jia; Tao Luo; Xin-Yao Yu; Zhen Jin; Bai Sun; Jin-Huai Liu; Xing-Jiu Huang, New Journal of Chemistry, 2013

Lepidocrocite (γ-FeOOH) nanoflakes were synthesized using a simple ethylene glycol (EG) mediated solution method. The obtained γ-FeOOH were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and ...

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Synthesis of Tetragonal and Orthorhombic Polymorphs of Hf3N4 by High-Pressure Annealing of a Prestructured Nanocrystalline Precursor

12-06-2013 | Ashkan Salamat; Andrew L. Hector; Benjamin M. Gray; Simon A. J. Kimber; Pierre Bouvier; Paul F. McMillan, Journal of the American Chemical Society, 2013

Hf3N4 in nanocrystalline form is produced by solution phase reaction of Hf(NEtMe)4 with ammonia followed by low-temperature pyrolysis in ammonia. Understanding of phase behavior in these systems is important because early transition-metal nitrides with the metal in maximum oxidation state are ...

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One-Step Synthesis of High-Coercivity L10-FePtAg Nanoparticles: Effects of Ag on the Morphology and Chemical Ordering of FePt Nanoparticles

11-06-2013 | Hanbin Wang; Panju Shang; Jun Zhang; Mingwei Guo; Yuping Mu; Quan Li; Hao Wang, Chemistry of Materials, 2013

High coercivity L10-ordered (FePt)1–xAgx nanoparticles (NPs) were directly synthesized using a one-step solution method without post-thermal annealing. The effect of silver additive on the morphology, chemical ordering, and magnetic properties of FePt NPs was studied. Magnetic measurements ...

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Growth of single crystalline TaON on yttria-stabilized zirconia (YSZ)

10-06-2013 | Author(s): Junguang Tao , J.W. Chai , L.M. Wong , Z. Zhang , J.S. Pan , S.J. Wang, Journal of Solid State Chemistry, 2013

Publication date: August 2013 Source:Journal of Solid State Chemistry, Volume 204 Author(s): Junguang Tao , J.W. Chai , L.M. Wong , Z. Zhang , J.S. Pan , S.J. Wang Owing to its high stability in aqueous solution and high quantum efficiency, tantalum based oxyntride (TaON) has ...

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Low Temperature Synthesis of High Alumina Cements by Novel Co‐Melt Precursors and Their Implementation as Castables with Some Micro Fine Additives

05-06-2013 | Vijay Kumar, Vinay Kumar Singh, Abhinav Srivastava, Journal of the American Ceramic Society, 2013

In the present investigations nano size high alumina cements (HAC) were prepared by very effective co‐melt precursor sintering technique from their metal nitrate precursors. The prime cementing phases observed were CA, CA2, and C12A7. The addition of nano structured cements in refractory ...

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Sunlight‐induced biosynthesis of silver nanoparticles by animal and fungus biomass and their characterization

04-06-2013 | Xuetuan Wei, Huacong Zhou, Lin Xu, Mingfang Luo, Huizhou Liu, Journal of Chemical Technology & Biotechnology, 2013

Abstract Background Biosynthesis of silver nanoparticles (AgNPs) is considered as a green method. Sunlight could induce the synthesis of AgNPs with bacteria and plant biomass, while animal and fungus biomass have not been investigated for synthesis of AgNPs under sunlight ...

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Heterobimetallic Cuprates Consisting of a Redox‐Switchable, Silicon‐Based Metalloligand: Synthesis, Structures, and Electronic Properties

04-06-2013 | Steffen Styra, Sandra González‐Gallardo, Felix Armbruster, Pascual Oña‐Burgos, Eric Moos, Matthias Vonderach, Patric ..., Chemistry - A European Journal, 2013

Abstract A series of bimetallic silyl halido cuprates consisting of the new tripodal silicon‐based metalloligand [κ3N‐Si(3,5‐Me2pz)3Mo(CO)3]− is presented (pz=pyrazolyl). This metalloligand is straightforwardly accessible by reacting the ambidentate ligand ...

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