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Understanding the Structural Evolution and Redox Mechanism of a NaFeO2–NaCoO2 Solid Solution for Sodium‐Ion Batteries

23-Jun-2016 | Kei Kubota, Takuya Asari, Hiroaki Yoshida, Naoaki Yaabuuchi, Hiromasa Shiiba, Masanobu Nakayama, Shinichi Komaba, Advanced Functional Materials, 2016

Na‐ion batteries have become promising candidates for large‐scale energy‐storage systems because of the abundant Na resources and they have attracted considerable academic interest because of their unique behavior, such as their electrochemical activity for the Fe3+/Fe4+ redox couple. The ...


Small‐angle X‐ray scattering as a useful supplementary technique to determine molecular masses of polyelectrolytes in solution

23-Jun-2016 | Beatrice Plazzotta, Jakob Stensgaard Diget, Kaizheng Zhu, Bo Nyström, Jan Skov Pedersen, Journal of Polymer Science Part B: Polymer Physics, 2016

ABSTRACT Determination of molecular masses of charged polymers is often nontrivial and most methods have their drawbacks. For polyelectrolytes, a new possibility for the determination of number‐average molecular masses is represented by small‐angle X‐ray scattering (SAXS) which allows fast ...


Cryogenic Ion Mobility-Mass Spectrometry: Tracking Ion Structure from Solution to the Gas Phase

23-Jun-2016 | Kelly A. Servage; Joshua A. Silveira; Kyle L. Fort; David H. Russell, Accounts of Chemical Research, 2016

ConspectusElectrospray ionization (ESI) combined with ion mobility-mass spectrometry (IM-MS) is adding new dimensions, that is, structure and dynamics, to the field of biological mass spectrometry. There is increasing evidence that gas-phase ions produced by ESI can closely resemble their ...


Phase Behavior and Densities of Propylene + Hexane Binary Mixtures to 585 K and 70 MPa

23-Jun-2016 | Rajendar R. Mallepally; Venkat S. Gadepalli; Babatunde A. Bamgbade; Nathaniel Cain; Mark A. McHugh, Journal of Chemical & Engineering Data, 2016

In this study, we report phase behavior data for propylene + hexane mixtures at temperatures of 295 to 468 K and pressures to 5.5 MPa and high-pressure mixture density data at temperatures of 295 to 584 K and pressures to 70 MPa. Both the phase behavior and density data are simultaneously ...


Sustainability, Vol. 8, Pages 586: Sustainable Assessment of Aerosol Pollution Decrease Applying Multiple Attribute Decision-Making Methods

23-Jun-2016 | Čereška, Audrius ; Zavadskas, Edmundas Kazimieras; Cavallaro, Fausto ; Podvezko, Valentinas ; Tetsman, Ina ; Grinber ..., Sustainability, 2016

Air pollution with various materials, particularly with aerosols, increases with the advances in technological development. This is a complicated global problem. One of the priorities in achieving sustainable development is the reduction of harmful technological effects on the environment and ...


Improved Hydrogen Production of Au–Pt–CdS Hetero‐Nanostructures by Efficient Plasmon‐Induced Multipathway Electron Transfer

22-Jun-2016 | Liang Ma, Kai Chen, Fan Nan, Jia‐Hong Wang, Da‐Jie Yang, Li Zhou, Qu‐Quan Wang, Advanced Functional Materials, 2016

The design of new functional materials with excellent hydrogen production activity under visible‐light irradiation has critical significance for solving the energy crisis. A well‐controlled synthesis strategy is developed to prepare an Au–Pt–CdS hetero‐nanostructure, in which each component of ...


Sulfur‐Enriched Conjugated Polymer Nanosheet Derived Sulfur and Nitrogen co‐Doped Porous Carbon Nanosheets as Electrocatalysts for Oxygen Reduction Reaction and Zinc–Air Battery

22-Jun-2016 | Yuezeng Su, Zhaoquan Yao, Fan Zhang, Hai Wang, Zoltan Mics, Enrique Cánovas, Mischa Bonn, Xiaodong Zhuang, Xinliang Feng, Advanced Functional Materials, 2016

Among the rising 2D soft materials, conjugated polymer nanosheets are one of the most promising and new classes of polymeric materials, which are rarely developed because of the challenge in controlling the dimensionality and lack of synthetic strategies. In this study, one kind of ...


Theoretical and Experimental Study on Boron β‐Diketonate Complexes with Intense Two‐Photon‐Induced Fluorescence in Solution and in the Solid State

22-Jun-2016 | Pierre‐Henri Lanoë, Bastien Mettra, Yuan Yuan Liao, Nathalie Calin, Anthony D'Aléo, Tomotaka Namikawa, Kenji Kamada, ..., ChemPhysChem, 2016

Abstract The front cover artwork is provided by the Chemistry for Optics group at the Laboratory of Chemistry, ENS Lyon, University of Lyon, France (Homepage: http://www.ens‐ The image shows how complexation of a simple chromophore with boron results in a spectacular ...


Mixed‐Valence o‐Iminobenzoquinone and o‐Iminobenzosemiquinonate Anion Radical Complexes of Cobalt: Valence Tautomerism

22-Jun-2016 | Suvendu Maity, Suman Kundu, Sachinath Bera, Thomas Weyhermüller, Prasanta Ghosh, European Journal of Inorganic Chemistry, 2016

2,4‐Di‐tert‐butyl‐N‐[2‐(phenylthio)]phenyl‐o‐iminobenzosemiquinonate anion radical (LSPhISQ·–) and o‐iminobenzoquinone (LSPhIQ) based mixed‐valence complexes of the types trans‐[CoII(LSPhISQ·–)(LSPhIQ)X] defined by Robin–Day Class III states, trans‐[CoII(LSPhISQ0.5·–)2X] {X = Cl–, 1; SCN– ...


The Effects of Low Oxygen Activity Conditions on the Phase Equilibria and Cation Occupancy of Strontium Barium Niobate

22-Jun-2016 | Jonathan A. Bock, Jason H. Chan, Yoed Tsur, Susan Trolier‐McKinstry, Clive A. Randall, Journal of the American Ceramic Society, 2016

Strontium barium niobate (SBN) is a tungsten bronze family ferroelectric which shows promising thermoelectric properties under reducing conditions. It is found here that the enhanced electrical conductivity of oxygen‐deficient SBN correlates with the formation of a NbO2 secondary phase. The ...


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