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Shape Uniformity Control of Metal-organic Framework Nanodisks via Surfactant and Substrate Synergetic Scissoring Effect and Their Fluorescent Sensing Properties

24-May-2016 | Naien Shi; Dan-dan Xu; Xinhui Zhou; Lin Song; Liang Li; Linghai Xie; Lian-Hui Wang; Ming-Dong Yi; Wei Huang, CrystEngComm, 2016

A surfactant and substrate synergetic chemical solution technique was promoted to synthesize uniform shaped MOF nanodisks. The hexaprism nanodisks of {[Eu2(MFDA)2(HCOO)2(H2O)6]•H2O}n (Eu-MFDA_HND, H2MFDA=9,9-dimethyl fluorene-2,7-dicarboxylic acid) were obtained on a supported substrate in the ...

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New insight into the structural, electrochemical and biological aspects of macroacyclic Cu(II) complexes derived from S-substituted dithiocarbazate schiff bases

22-May-2016 | Author(s): May Lee Low, Laure Maigre, Mohamed Ibrahim M. Tahir, Edward R.T. Tiekink, Pierre Dorlet, Régis ..., European Journal of Medicinal Chemistry, 2016

Publication date: 14 September 2016 Source:European Journal of Medicinal Chemistry, Volume 120 Author(s): May Lee Low, Laure Maigre, Mohamed Ibrahim M. Tahir, Edward R.T. Tiekink, Pierre Dorlet, Régis Guillot, Thahira Begum Ravoof, Rozita Rosli, Jean-Marie Pagès, ...

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Mineralization of chlorobenzene in aqueous medium by anodic oxidation and electro-Fenton processes using Pt or BDD anode and carbon felt cathode

22-May-2016 | Author(s): Hicham Zazou, Nihal Oturan, Mutlu Sönmez-Çelebi, Mohamed Hamdani, Mehmet A. Oturan, Journal of Electroanalytical Chemistry, 2016

Publication date: 1 August 2016 Source:Journal of Electroanalytical Chemistry, Volume 774 Author(s): Hicham Zazou, Nihal Oturan, Mutlu Sönmez-Çelebi, Mohamed Hamdani, Mehmet A. Oturan This study focuses on the in situ destruction of pesticide chlorobenzene (CB) by using two ...

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Preparation of a novel silk microfiber covered by AgCl nanoparticles with antimicrobial activity

21-May-2016 | Qifan Xie, Zongpu Xu, Binhui Hu, Xiuling He, Liangjun Zhu, Microscopy Research and Technique, 2016

Abstract We prepared silk fibroin microfibers in which silver chloride (AgCl) nanoparticles were dispersed, by sequential dipping of microfibers obtained using alkaline hydrolysis in alternating solutions of silver nitrate and potassium chloride. Scanning and transmission electron microscopy ...

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Materials, Vol. 9, Pages 401: Phase Changes of Monosulfoaluminate in NaCl Aqueous Solution

21-May-2016 | Yoon, Seyoon ; Ha, Juyoung ; Chae, Sejung Rosie; Kilcoyne, David A.; Jun, Yubin ; Oh, Jae Eun; Monteiro, Paulo J.M., Materials, 2016

Monosulfoaluminate (Ca4Al2(SO4)(OH)12∙6H2O) plays an important role in anion binding in Portland cement by exchanging its original interlayer ions (SO42− and OH−) with chloride ions. In this study, scanning transmission X-ray microscope (STXM), X-ray absorption near edge structure (XANES) ...

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3‐(3,4,5‐Trimethoxybenzylidene)‐2,4‐pentanedione: Design of a Novel Photostabilizer with In‐vivo SPF Boosting Properties and Its Use in Developing Broad‐spectrum Sunscreen Formulations

20-May-2016 | Ratan K. Chaudhuri, Moses A. Ollengo, Parvesh Singh, Bice S. Martincigh, International Journal of Cosmetic Science, 2016

Abstract Objective The study concerned the synthesis of a novel photostabilizer based on benzylidenepentanedione chemistry and the evaluation of its potential in developing a broad‐spectrum sunscreen formulation containing ...

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α‐Helical Structures of Oligopeptíides with an Alternating l‐Leu‐Aib Segment

20-May-2016 | Yosuke Demizu, Koyo Okitsu, Hiroko Yamashita, Mitsunobu Doi, Takashi Misawa, Makoto Oba, Masakazu Tanaka, Masaaki Ku ..., European Journal of Organic Chemistry, 2016

We investigated the preferred conformations of l‐Leu‐Aib‐alternating peptides, Boc‐(l‐Leu‐Aib)n‐OMe (n = 1: 1, 2: 2, 3: 3, 4: 4, 5: 5), in solution and in the crystalline state. Peptides that contain more than six amino acid residues fold into right‐handed (P) helical structures. Specifically, ...

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Size‐Controlled Formation of Noble‐Metal Nanoparticles in Aqueous Solution with a Thiol‐Free Tripeptide

20-May-2016 | Stefano Corra, Urszula Lewandowska, Edmondo M. Benetti, Helma Wennemers, Angewandte Chemie International Edition, 2016

Monodisperse noble‐metal nanoparticles (in the example PdNPs) can be formed in aqueous solution in the presence of a thiol‐free tripeptide as shown by H. Wennemers and co‐workers in their Communication (DOI: 10.1002/anie.201510337). The cover depicts how the peptide upon complexation to Pd2+ ...

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High‐Performance Multifunctional Thermoplastic Composites Enhanced by Aligned Buckypaper 

20-May-2016 | Zhongrui Li, Jin Gyu Park, Zhiyong Liang, Advanced Engineering Materials, 2016

High‐performance lightweight composites are sizably manufactured by impregnating continuous aligned carbon nanotube sheet (buckypapers) with self‐reinforcing polyphenylene (Parmax) solution and followed by hot‐press. The high processing pressure flattens nanotubes, which preferably π‐stack with ...

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Hierarchically Mesoporous o‐Hydroxyazobenzene Polymers: Synthesis and Their Applications in CO2 Capture and Conversion

20-May-2016 | Guipeng Ji, Zhenzhen Yang, Hongye Zhang, Yanfei Zhao, Bo Yu, Zhishuang Ma, Zhimin Liu, Angewandte Chemie International Edition, 2016

Abstract The synthesis of hierarchically mesoporous polymers with multiple functionalities is challenging. Herein we reported a template‐free strategy for synthesis of phenolic azo‐polymers with hierarchical porous structures based on diazo‐coupling reaction in aqueous solution under mild ...

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