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Charge compensation assisted enhancement of photoluminescence in combustion derived Li+ co-doped cubic ZrO2:Eu3+nanophosphors

22-Sep-2016 | Prakashbabu D; Ramalingam H. B.; Hari Krishna Rajan; B. M. Nagabhushana; Chandramohan R.; Chikkadasappa Shivakumara; ..., Physical Chemistry Chemical Physics, 2016

Red light emitting cubic Zr0.99Eu0.01O2: Li+ (0 – 9 mol%) nanoparticles are synthesized by a low temperature, self-propagating solution combustion method using oxalyl di-hydrazide (ODH) as fuel. In this study, we report systematic investigation of the effect of lithium ion (Li+) concentration on ...


Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide

22-Sep-2016 | Juan-Pablo Correa-Baena; Elham Halvani Anaraki; Ahmad Kermanpur; Ludmilla Steier; Konrad Domanski; Taisuke Matsui; W ..., Energy & Environmental Science, 2016

Perovskite solar cells (PSCs) are one of the most promising lab-scale technologies to deliver inexpensive solar electricity. Low-temperature planar PSCs are particularly suited for large-scale manufacturing. Here, we propose a simple, solution-processed technological approach for depositing SnO2 ...


Copolymers from norbornene and norbornadiene with organized morphologies and high Tg values obtained via ROMP with highly reactive [RuCl3(PCy3)2] complex

22-Sep-2016 | Camila P. Ferraz; Larissa R. Fonseca; Vinicius Tomazetti; Felipe C. S. Silva; Benedito S. Lima-Neto; Valdemiro P. Ca ..., New Journal of Chemistry, 2016

The [(RuCl3(PCy3)2] complex presented high reactivity for Ring Opening Metathesis Polymerization (ROMP) of norbornadiene (NBD) in non-degassed solution upon addition of ethyl diazoacetate (EDA). Quantitative yields of polyNBD were obtained instantaneously at 25 °C. ROMP of norbornene (NBE) better ...


Counterion-Dominating Chirality Transfer between Chiral and Achiral Polyoxometalates

22-Sep-2016 | Lei Shi; Fengrui Jiang; Bao Li; Lixin Wu, Dalton Transactions, 2016

We show that chirality transfer from chiral polyoxometalates to achiral polyoxometalates can occur in aqueous solution with unexpected selectivity of surrounding counterions. In comparison with the sodium ions, protonated dimethylammonium couterions play a critical role in shortening the ...


A unique (3,10)-connected magnesium/nickel-based metal−organic framework constructed from unusual kgd supermolecular building layer via mixed linkers and solid solution approach

22-Sep-2016 | Yong-Jie Geng; Ai-Qin Zhang; Xian-Kun Wu; Dong-Xu Xue; Zhihong Liu, CrystEngComm, 2016

Hydrothermal reaction between mixed linkers and mixed metals, alkaline earth 4MgCO3•Mg(OH)2•5H2O and 3d Ni(CH3COO3)2•4H2O, a unique metal-organic framework of SNNU-99 was impressively isolated and structurally characterized. SNNU-99 is constructed from an unprecedented decanuclear Mg/Ni-based ...


Theoretical prediction of coordination environments and stability constants of lanthanum lactate complexes in solution

22-Sep-2016 | Lindsay E. Roy; Leigh R. Martin, Dalton Transactions, 2016

Using Density Functional Theory calculations in combination with explicit solvent and a continuum solvent model, this work sets out to understand the coordination environment and relevant thermodynamics of La(iii)-lactate complexes. Calculations focus on the coordination modes for the complexes ...


Formation of Simple single-tailed Vesicles Mediated by Lipophilic Solid Surface

22-Sep-2016 | Na Du; Xiaoyu Zhu; Ruiying Song; Shue Song; Wan Guo Hou, Soft Matter, 2016

Adsorption and aggregation of surfactants at solid-liquid interfaces were fairly well understood, but there was limited knowledge regarding the effect of solid surface presence on aggregate structures in bulk solution. Except fatty acids system, most of the simple single-tailed surfactants (STS) ...


A new highly effective fluorescent probe for Al3+ ions and its application in practical samples

18-Sep-2016 | Author(s): Fei Wang, Yuling Xu, Stephen Opeyemi Aderinto, Hongping Peng, Han Zhang, Huilu Wu, Journal of Photochemistry and Photobiology A: Chemistry, 2016

Publication date: 1 January 2017 Source:Journal of Photochemistry and Photobiology A: Chemistry, Volume 332 Author(s): Fei Wang, Yuling Xu, Stephen Opeyemi Aderinto, Hongping Peng, Han Zhang, Huilu Wu A new 1,8-naphthalimide derivative, N-allyl-4-[3,3′-((2-aminoethyl)azanediyl) ...


Decomposition of dimethyl phthalate in aqueous solution by UV–LED/TiO2 process under periodic illumination

18-Sep-2016 | Author(s): Young Ku, Shiau-Ju Shiu, Hsuan-Chih Wu, Journal of Photochemistry and Photobiology A: Chemistry, 2016

Publication date: 1 January 2017 Source:Journal of Photochemistry and Photobiology A: Chemistry, Volume 332 Author(s): Young Ku, Shiau-Ju Shiu, Hsuan-Chih Wu The effect of controlled periodic illumination on the photonic efficiency and temporal decomposition behavior of dimethyl ...


Amino‐functionalized cotton fiber for enhanced adsorption of active brilliant red X‐3B from aqueous solution

18-Sep-2016 | Hui Deng, JiaHong Ning, XiaoNing Wang, Microscopy Research and Technique, 2016

Abstract An amino‐functionalized sorbent (ACF) was prepared by grafting amine group onto cotton fiber (CF) using tetraethylenepentamine (TEPA). The resulting composite was characterized using various instrumental techniques such as scanning electron microscopy (SEM), Fourier transformed ...


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