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1,1'-Bis(diphenylphosphino)ferrocene
| 1,1'-Bis(diphenylphosphino)ferrocene |
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| Other names |
1,1'-Bis(diphenylphosphino)ferrocene, 1,1'-Ferrocenediyl-bis(diphenylphosphine), Dppf, 1,1'-Ferrocenebis(diphenylphosphine) |
| Identifiers |
| CAS number |
12150-46-8 |
| PubChem |
635956 |
| SMILES |
C1=CC=C(C=C1)P([C-]2C=CC=C2)C3=CC=CC=C3 .C1=CC=C(C=C1)P([C-]2C=CC=C2)C3=CC=CC=C3.[Fe+2] |
| InChI |
InChI=1/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17- -13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/q2*-1;+2 |
| Properties |
| Molecular formula |
C34H28FeP2 |
| Molar mass |
554.391 |
| Melting point |
181 - 183 °C
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| Hazards |
| Main hazards |
Toxic |
| R-phrases |
R25 |
| S-phrases |
S28A S45 |
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)
Infobox disclaimer and references |
1,1'-Bis(diphenylphosphino)ferrocene, commonly abbreviated dppf, is a substituted phosphine commonly used, as are other phosphines, as a ligand in organometallic chemistry. It contains a ferrocene moiety in its backbone, and is closely related to other bridged diphenylphosphines such as 1,1-bis(diphenylphosphino)methane (dppm) and 1,2-bis(diphenylphosphino)ethane (dppe). It is commercially available, and is usually purchased rather than synthesized.
See also
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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "1,1'-Bis(diphenylphosphino)ferrocene". A list of authors is available in Wikipedia.
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