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Room-Temperature, Water-Promoted, Radical-Coupling Reactions of Phenols with tert-Butyl Nitrite

DOI: 10.1055/s-0036-1589038

A radical–radical cross-coupling reaction of phenols with tert-butyl nitrite has been developed with the use of water as an additive. This method allows the construction of C–N bonds under an air atmosphere at room temperature, providing the ortho-nitrated phenol derivative in moderate to good yields.

© Georg Thieme Verlag Stuttgart · New York

Artikel in Thieme eJournals:
Inhaltsverzeichnis  |  Abstract  |  Volltext

Authors:   Wen-Ting Wei; Wen-Ming Zhu; Weida Liang; Yi Wu; Hui-Yan Huang; Yi-Ling Huang; Junfei Luo; Hongze Liang
Journal:   Synlett
Volume:   357
edition:   eFirst
Year:   2017
Pages:   3849
DOI:   10.1055/s-0036-1589038
Publication date:   21-Jun-2017
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  • Georg Thieme Verlag
  • coupling reactions
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