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Reactivity of Seven-Membered-Ring trans-Alkenes with Electrophiles

DOI: 10.1055/s-0036-1588451

Seven-membered-ring trans-alkenes containing a silicon–oxygen bond reacted rapidly with oxygen gas and electron-deficient alkenes and alkynes to give products with high selectivity. Addition of an electron-donating substituent or incorporating additional strain increased the reactivity by over two orders of magnitude. These results indicate that release of strain is not the only driving force for reactivity.

© Georg Thieme Verlag Stuttgart · New York

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Inhaltsverzeichnis  |  Abstract  |  Volltext

Authors:   Jillian R. Sanzone; K. A. Woerpel
Journal:   Synlett
Volume:   13
edition:   eFirst
Year:   2017
Pages:   2956
DOI:   10.1055/s-0036-1588451
Publication date:   21-Jun-2017
Facts, background information, dossiers
  • alkenes
  • Thieme
  • selectivity
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