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Facile Polymerization of Water and Triple-Bond Based Monomers toward Functional Polyamides

Water is an abundant, natural, and sustainable resource. However, it has not been used as a monomer for the construction of polymers. In this paper, we take this challenge and develop a new polymerization of water and triple-bond based monomers of isocyanides and bromoalkynes, and polyamides with high molecular weights (up to 41 700) and stereoregularities (the fraction of Z-isomer generally higher than 80%) are obtained in excellent yields (up to 98.1%) under mild reaction conditions. The polymers possess good solubility and exhibit high thermal stability and refractive index. The tetraphenylethene-containing polymers show the unique aggregation-enhanced emission (AEE) characteristics. Moreover, thanks to their containing bromoacrylamide groups in the main chains, these polyamides could be easily postmodified through different reactions, providing a convenient platform for polymer functionalization. Thus, this work not only established a stereoselective polymerization of water and triple-bond based monom...

Authors:   Jie Zhang; Wenjie Wang; Yong Liu; Jing Zhi Sun; Anjun Qin; Ben Zhong Tang
Journal:   Macromolecules
Year:   2017
DOI:   10.1021/acs.macromol.7b01592
Publication date:   18-Oct-2017
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  • aggregation
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