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A Series of Weakley-type Polyoxomolybdates: Synthesis, Characterization, and Magnetic Properties by a Combined Experimental and Theoretical Approach

Using DCC as the dehydrating agent, a series of Weakley-type polyoxomolybdates [Bu4N]3{Ln[Mo5O13(OMe)4(NO)]2} (Ln = Tb, Dy, Ho, Er) were synthesized in a one-pot reaction and structurally characterized by elemental, IR, UV–vis analysis, PXRD, and single-crystal X-ray diffraction. Furthermore, the static and dynamic measurements were utilized to investigate their magnetic performances. Typically, slow relaxation of magnetization was observed for Dy analogues with an energy barrier for the reversal of the magnetization of 50 K, which is the highest barrier height observed on the polyoxomolybdates-based single-molecule magnets (SMMs). For a deep understanding of the appearance of the SMM behavior on Weakley-type polyoxomolybdates series, ab initio calculations on {Dy[Mo5O13(OMe)4(NO)]2}3– have been conducted.

Authors:   Shan She; Chen Gao; Kun Chen; Aruuhan Bayaguud; Yichao Huang; Bing-Wu Wang; Song Gao; Yongge Wei
Journal:   Inorganic Chemistry
Year:   2018
DOI:   10.1021/acs.inorgchem.7b01971
Publication date:   11-Jan-2018
Facts, background information, dossiers
  • magnetization
  • magnetic properties
  • Energy
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