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Van't Hoff analysis in chiral chromatography


The present review discusses the theory and application of van't Hoff analysis in chiral chromatography, with main focus on liquid chromatography. The topics considered include the physical meaning of van't Hoff equation's parameters, interpretation of thermodynamic data in terms of retention and enantioseparation mechanisms, abnormal behavior of van't Hoff plots, and best practices to avoid biased results.

This article is protected by copyright. All rights reserved

Authors:   Leonid D. Asnin, Maria V. Stepanova
Journal:   Journal of Separation Science
Year:   2018
Pages:   n/a
DOI:   10.1002/jssc.201701264
Publication date:   11-Jan-2018
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