My watch list
my.chemeurope.com  
Login  

Facet-Dependent Rock-Salt Reconstruction on the Surface of Layered Oxide Cathodes

The surface configuration of pristine layered oxide cathode particles for Li-ion batteries significantly affects the electrochemical behavior, which is generally considered to be a thin rock-salt layer in the surface. Unfortunately, aside from its thin nature and spatial location on the surface, the true structural nature of this surface rock-salt layer remains largely unknown, creating the need to understand its configuration and the underlying mechanisms of formation. Using scanning transmission electron microscopy, we have found a correlation between the surface rock-salt formation and the crystal facets on pristine LiNi0.80Co0.15Al0.05O2 primary particles. It is found that the originally (014̅) and (003) surfaces of the layered phase result in two kinds of rock-salt reconstructions: the (002) and (111) rock-salt surfaces, respectively. Stepped surface configurations are generated for both reconstructions. The (002) configuration is relatively flat with monatomic steps while the (111) configuration sho...

Authors:   Hanlei Zhang; Brian M. May; Jon Serrano-Sevillano; Montse Casas-Cabanas; Jordi Cabana; Chongmin Wang; Guangwen Zhou
Journal:   Chemistry of Materials
Year:   2018
DOI:   10.1021/acs.chemmater.7b03901
Publication date:   18-Jan-2018
Facts, background information, dossiers
More about American Chemical Society Publications
Your browser is not current. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE