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Plasmon hybridization, the electromagnetic analog of molecular orbital theory, provides a simple and intuitive method to describe the plasmonic response of complex nanostructures from the combination of the responses of their individual constituents. Here, we follow this approach to investigate the optical properties of periodic arrays of plasmonic nanoparticles with multiparticle unit cells. These systems support strong collective lattice resonances, arising from the coherent multiple scattering enabled by the lattice periodicity. Due to the extended nature of these modes, the interaction between them is very different from that among localized surface plasmons supported by individual nanoparticles. This leads to a much richer hybridization scenario, which we exploit here to design periodic arrays with engineered properties. These include arrays with two-particle unit cells, in which the interaction between the individual lattice resonances can be canceled or maximized by controlling the relative positio...
| Authors: | Sebastian Baur; Stephen Sanders; Alejandro Manjavacas | |
| Journal: | ACS Nano | |
| Year: | 2018 | |
| DOI: | 10.1021/acsnano.7b08206 | |
| Publication date: | 18-Jan-2018 |
We recently generalized the formerly alignment-dependent multivariate image analysis applied to quantitative structure–activity relationships (MIA-QSAR) method through the application of the discrete Fourier transform (DFT), allowing for its application to noncongruent and structurally dive ... more
Proteomic Analysis of the Downstream Signaling Network of PARP1
Poly-ADP-ribosylation (PARylation) is a protein posttranslational modification (PTM) that is critically involved in many biological processes that are linked to cell stress responses. It is catalyzed by a class of enzymes known as poly-ADP-ribose polymerases (PARPs). In particular, PARP1 is ... more
Oxygen Activation and Energy Conservation by Cytochrome c Oxidase
This review focuses on the type A cytochrome c oxidases (CcO), which are found in all mitochondria and also in several aerobic bacteria. CcO catalyzes the respiratory reduction of dioxygen (O2) to water by an intriguing mechanism, the details of which are fairly well understood today as a r ... more
Rohm and Haas Powder Coatings is delighted to announce that its Reading, Pennsylvania, facility is the first site in the world to receive the RCMS® Site Certification awarded by the American Chemical Council (ACC). When Raj Gupta, Chairman and CEO of Rohm and Haas Company, became Chairman ... more
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