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Frontispiece: Reduction of Carbonyl Groups by Uranium(III) and Formation of a Stable Amide Radical Anion

Reduction of organic ketones, esters and amides by UIII[N(SiMe3)2]3 resulted in a variety of uranium(IV) compounds. The fates of the organic fragments ranged from reversible radical coupling, to bond cleavage, group transfer or one‐electron reduction. In particular, the first example of a stable, charge‐separated amide radical was established, supported by magnetic, UV‐Vis‐NIR, electrochemical and EPR measurements, as well as computational studies. For more details see the Full Paper by E. J. Schelter et al. on page 826 ff.

Authors:   Kimberly C. Mullane, Thibault Cheisson, Eiko Nakamaru‐Ogiso, Brian C. Manor, Patrick J. Carroll, Eric J. Schelter
Journal:   Chemistry - A European Journal
Volume:   24
edition:   4
Year:   2018
Pages:   n/a
DOI:   10.1002/chem.201880464
Publication date:   19-Jan-2018
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