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Enantioselective Synthesis of Aminodiols by Sequential Rh‐Catalysed Oxyamination/Kinetic Resolution. Expanding the Substrate Scope of Amidine‐Based Catalysis

Regio‐ and stereoselective oxyamination of dienes through a tandem rhodium catalysed aziridination‐nucleophilic opening affords racemic oxazolidinone derivatives, which undergo a kinetic resolution acylation process using ABCs (amidine‐based catalysts) achieving s values up to 117. This protocol was applied to the enantioselective synthesis of sphingosine.

Authors:   Joan Guasch, Irene Giménez, Ignacio Funes-Ardoiz, Isabel Matheu, Feliu Maseras, Sergio Castillón, Yolanda Díaz, Miguel Bernús
Journal:   Chemistry - A European Journal
Year:   2018
Pages:   n/a
DOI:   10.1002/chem.201705670
Publication date:   17-Jan-2018
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