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Molbank, Vol. 2018, Article M987: 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione

Molbank, Vol. 2018, Article M987: 5,5′-Bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione

Molbank doi: 10.3390/M987

Authors: Andreas Kalogirou Panayiotis Koutentis

Stille coupling of 5,5′-dichloro-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (8) with 9-decyl-3-[5-(tributylstannyl)thien-2-yl]-9H-carbazole and Pd(Ph3P)2Cl2 in PhMe, at ca. 110 °C, for 2 h, gave 5,5′-bis[5-(9-decyl-9H-carbazol-3-yl)thien-2-yl]-4H,4′H-[3,3′-bi(1,2,6-thiadiazine)]-4,4′-dione (7) in 51% yield. The latter is investigated as an oligomer donor for organic photovoltaics.

Authors:   Kalogirou, Andreas S.; Koutentis, Panayiotis A.
Journal:   Molbank
Volume:   2018
edition:   1
Year:   2018
Pages:   M987
DOI:   10.3390/M987
Publication date:   08-Mar-2018
Facts, background information, dossiers
  • Stille Coupling
  • organic photovoltaics
More about Molecular Diversity Preservation International
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