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Hydration and alkoxylation of alkynes catalyzed by NHC–Au–OTf

The NHC–Au–OTf [NHC = 1,3-bis(2,6-di-isopropylphenyl)-imidazol-2-ylidene] catalyst was tested in the alkoxylation and hydration of alkynes in a wide set of neoteric solvents for the first time. We found that most of these solvents (ethyl lactate, glycerol, propylene carbonate, d-limonene, γ-valerolactone, an

Authors:   Mattia Gatto; Walter Baratta; Paola Belanzoni; Leonardo Belpassi; Alessandro Del Zotto; Francesco Tarantelli; Daniele Zuccaccia
Journal:   Green Chemistry
Volume:   20
edition:   9
Pages:   2125
DOI:   10.1039/C8GC00508G
Facts, background information, dossiers
  • Alkoxylation
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