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Low-valent magnesium(I)-catalyzed cyanosilylation of ketones

The magnesium(i) complex [(XylNacnac)Mg]2 was employed as a highly efficient catalyst for the cyanosilylation of a variety of ketones with trimethylsilyl cyanide under mild conditions. In contrast to the traditional stoichiometric use of magnesium(i) complexes, 1 provides the first example of a truly catalyt

Authors:   Weifan Wang; Man Luo; Jia Li; Sumod A. Pullarkat; Mengtao Ma
Journal:   Chemical Communication
Volume:   54
edition:   24
Pages:   3042
DOI:   10.1039/C8CC00826D
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  • complexes
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