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Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates via direct dehydrogenative C(sp2)–O cross-coupling

An efficient olefination protocol for the oxidative dehydrogenation of phenols and acrylates has been achieved using a palladium catalyst and O2 as the sole oxidant. This reaction exhibits high regio- and stereo-selectivity (E-isomers) with moderate to excellent isolated yields and a wide substrate scope (32

Authors:   Yun-Bin Wu; Dan Xie; Zhong-Lin Zang; Cheng-He Zhou; Gui-Xin Cai
Journal:   Chemical Communication
Volume:   54
edition:   35
Pages:   4437
DOI:   10.1039/C8CC01226A
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