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Beyond geminal diesters: increasing the scope of metal-mediated vinylcyclopropane annulations while decreasing pre-activation

The utilization of unactivated substrates in annulation reactions provides access to complex products without the need for subsequent removal of the activating group. Vinylcyclopropanes (VCPs), occurring naturally in several monoterpene natural products, are an important building block for organic chemistry,

Authors:   Duncan K. Brownsey; Evgueni Gorobets; Darren J. Derksen
Journal:   Organic & Biomolecular Chemistry
Volume:   16
edition:   19
Pages:   3506
DOI:   10.1039/C8OB00593A
Facts, background information, dossiers
  • natural products
  • Annulation
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