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Solvation dynamics in polar solvents and imidazolium ionic liquids: failure of linear response approximations

This study presents the large scale computer simulations of two common fluorophores, N-methyl-6-oxyquinolinium betaine and coumarin 153, in five polar or ionic solvents. The validity of linear response approximations to calculate the time-dependent Stokes shift is evaluated in each system. In most studied sy

Authors:   Esther Heid; Christian Schröder
Journal:   Physical Chemistry Chemical Physics
Volume:   20
edition:   7
Pages:   5246
DOI:   10.1039/C7CP07052G
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