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Thermo-responsive recoverable polymeric inhibitors for the resolution of racemic amino acids

Novel polymeric inhibitors with lower critical solution temperatures in water were prepared and used to mediate the crystallization of racemic asparagine monohydrate, leading to chiral separation with 88.6 ee%. They could be recollected by simply elevating the temperature with a high yield of around 95% and

Authors:   Xichong Ye; Jie Zhang; Jiaxi Cui; Xinhua Wan
Journal:   Chemical Communication
Volume:   54
edition:   22
Pages:   2785
DOI:   10.1039/C8CC00333E
Facts, background information, dossiers
  • water
  • temperature
  • solution
  • amino acids
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