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Universal kinetic solvent effects in acid-catalyzed reactions of biomass-derived oxygenates

The rates of Brønsted-acid-catalyzed reactions of ethyl tert-butyl ether, tert-butanol, levoglucosan, 1,2-propanediol, fructose, cellobiose, and xylitol were measured in solvent mixtures of water with three polar aprotic cosolvents: γ-valerolactone; 1,4-dioxane; and tetrahydrofuran. As the water content of t 2018 Energy and Environmental Science HOT Articles

Authors:   Theodore W. Walker; Alex K. Chew; Huixiang Li; Benginur Demir; Z. Conrad Zhang; George W. Huber; Reid C. Van Lehn; James A. Dumesic
Journal:   Energy & Environmental Science
Volume:   11
edition:   3
Pages:   617
DOI:   10.1039/C7EE03432F
Facts, background information, dossiers
  • water
  • xylitol
  • tetrahydrofuran
  • solvent effects
  • fructose
  • biomass
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