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Organocatalytic asymmetric synthesis of benzazepinoindole derivatives with trifluoromethylated quaternary stereocenters by chiral phosphoric acid catalysts

An enantioselective aza-Friedel–Crafts reaction of trifluoromethyl dihydrobenzoazepinoindoles with pyrroles catalyzed by a chiral spirocyclic phosphoric acid was developed. This methodology provides a facile route to CF3- and pyrrole-containing benzazepinoindoles bearing quaternary stereocenters in good yiel Catalysis & biocatalysis in OBC

Authors:   Abdul Rahman; En Xie; Xufeng Lin
Journal:   Organic & Biomolecular Chemistry
Volume:   16
edition:   8
Pages:   1367
DOI:   10.1039/C8OB00055G
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