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Flexible and rigid dicarboxylic acids enable the assembly of achiral and chiral 3D Co(II) metal–organic frameworks

Two novel 3D Co(ii) metal–organic frameworks induced by flexible and rigid dicarboxylic acids [Co3(μ3-OH)(1,4-ttb)3(sa)]·3H2O (1) and Co2(μ3-OH)(1,4-ttb)(4,4′-bpdc) (2) (1,4-ttb = 1-(tetrazo-5-yl)-4-(triazo-1-yl)benzene, sa = succinic acid and 4,4′-bpdc = biphenyl-4,4′-dicarboxylic acid) have been successful

Authors:   Chunhua Gong; Haiyang Guo; Xianghua Zeng; Hao Xu; Qingdao Zeng; Junyong Zhang; Jingli Xie
Journal:   Dalton Transactions
Volume:   47
edition:   20
Pages:   6917
DOI:   10.1039/C8DT00600H
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