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Amido Ca(II) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes

A series of amido Ca complexes LCa[N(SiMe3)2](THF) (1−4) coordinated by Schiff base ligands L1−4 were synthesized via amine elimination reaction between proligands L1−4H and bisamido complex Ca[N(SiMe3)2]2(THF)2 in good yields. Unlike Ca[N(SiMe3)2]2(THF)2 the reactions of M[N(SiMe3)2]2(THF)2 (M = Yb, Sm) wit

Authors:   Alexander Trifonov; Natalia Forosenko; Ivan Basalov; Anton Cherkasov; Georgii K Fukin; Elena Shubina
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01130C
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  • complexes
  • WIT
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