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Chelation-assisted C–N cross-coupling of phosphinamides and aryl boronic acids with copper powder at room temperature

A protocol for the chelation-assisted C–N cross-coupling of phosphinamides and aryl boronic acids with copper powder under an oxygen atmosphere is reported. This reaction proceeds efficiently to afford fully substituted unsymmetrical N-arylation phosphinamides at room temperature in excellent yields. Diverse unstab Synthetic methodology in OBC

Authors:   Yao Peng; Jian Lei; Renhua Qiu; Lingteng Peng; Chak-Tong Au; Shuang-Feng Yin
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB00907D
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