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Synthesis of ternary group 13/15 chain compounds

Herein we present the synthesis and characterisation of the seven-membered group 13/15 chain compound HB{N(H)PtBu2BH3}2 (3) obtained from the reaction of tBu2PNH2 (1) with Me2S·BH3. Furthermore, we describe the synthesis of the aluminium and gallium compounds tBu2PN(H)AltBu2N(H)P(H)tBu2 (4) and tBu2(H)PN(H)GatBu3 (

Authors:   Marcel Köster; Annikka Kreher; Carsten von Hänisch
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01119B
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