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Ligand-promoted ruthenium-catalyzed meta C–H chlorination of arenes using N-chloro-2,10-camphorsultam

A practical meta C–H chlorination protocol is established via a Ru(0)-catalyzed ortho-metalation strategy. The use of N-chloro-2,10-camphorsultam as a new chlorinating agent is crucial for the success of the current reaction and an N-heterocyclic carbene (NHC) ligand could significantly enhance the reactivity of th

Authors:   Zhoulong Fan; Heng Lu; Zhen Cheng; Ao Zhang
Journal:   Chemical Communication
DOI:   10.1039/C8CC03195A
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