Molbank, Vol. 2018, Article M995: 2,4-Bis[(2,6-diisopropylphenyl)imino]-3-methylpentan-3-ol
Molbank doi: 10.3390/M995
Authors:
Wenting Sun
Wenyu Kong
Qing Du
Shumiao Zhang
Lihua Guo
Zhe Liu
The compound 2,4-bis[(2,6-diisopropylphenyl)imino]-3-methylpentan-3-ol was synthesized with a yield of approximately 80% by the reaction of 2,4-bis(2,6-diisopropylphenylimino)pentan-3-one with trimethylaluminum, which was followed by hydrolysis with an aqueous NaOH solution. A chemoselective addition to the C=O bond occurred in this reaction. The structure was confirmed by X-ray crystallography. This new compound was also fully characterized by 1H, 13C-NMR spectroscopy and 1H-13C HSQC spectroscopy, mass spectrometry and elemental analysis.
Authors: |
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Sun, Wenting ; Kong, Wenyu ; Du, Qing ; Zhang, Shumiao ; Guo, Lihua ; Liu, Zhe |
Journal: |
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Molbank
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Volume: |
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2018 |
edition: |
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2 |
Year: |
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2018 |
Pages: |
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M995 |
DOI: |
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10.3390/M995
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Publication date: |
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12-May-2018 |