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Molbank, Vol. 2018, Article M993: Octahydro-1H,5H,7H-dipyrrolo[1,2-c:1′,2′-f][1,3,6]oxadiazocine-5-thione

Molbank, Vol. 2018, Article M993: Octahydro-1H,5H,7H-dipyrrolo[1,2-c:1′,2′-f][1,3,6]oxadiazocine-5-thione

Molbank doi: 10.3390/M993

Authors: R. Alan Aitken Karamat Ali

A minor byproduct in the reaction of (S)-prolinol with thiophosgene in the presence of triethylamine is identified as a novel tricyclic dipyrrolidino-1,3,6-oxadiazocane-2-thione, the first example of such a ring system, and a representative of the uncommon, but useful 1,3,6-oxadiazocanes. A mechanism is proposed for its formation.

Authors:   Aitken, R. Alan; Ali, Karamat
Journal:   Molbank
Volume:   2018
edition:   2
Year:   2018
Pages:   M993
DOI:   10.3390/M993
Publication date:   27-Apr-2018
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