My watch list
my.chemeurope.com  
Login  

Temperature-controlled spontaneous resolution of enantiomerically threefold interpenetrating arm-shaped MOFs with achiral symmetrical ligands

Publication date:

Available online 7 June 2018


Source:Inorganic Chemistry Communications

Author(s): Gui-Lin Wen, Guo-Ping Yang, Ping Liu, Bo Liu, Yao-Yu Wang

Hydrothermal reaction of flexible 4,4′-oxybis(benzoic acid) (H2oba), semi-rigid 2,5-bis(4-pyridyl)-1,3,4-thiadiazole (bpt) and Cu(OH)2 led to an interesting 2D → 3D polythreaded architecture of MOF [Cu2(bpt)2(oba)2(H2O)]n·4nH2O (1). Accomplished with the rising synthesis temperature, two chiral MOFs [Cu4(bpt)4(oba)4]n (L-2 and D-2), have been obtained from the congenetic nonchiral precursors upon spontaneous resolution, which represent a rarely example of temperature-induced threefold interpenetrating enantiomerically arm-shaped MOFs constructed from achiral symmetrical ligands.
Graphical abstract




Authors:   Author(s): Gui-Lin Wen, Guo-Ping Yang, Ping Liu, Bo Liu, Yao-Yu Wang
Journal:   Inorganic Chemistry Communications
Year:   2018
Publication date:   10-Jun-2018
Facts, background information, dossiers
More about Elsevier
Your browser is not current. Microsoft Internet Explorer 6.0 does not support some functions on Chemie.DE