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Coordination and metal ion-mediated transformation of a polydentate ligand containing oxime, hydrazone and picolinoyl functionalities

Publication date:

Available online 5 June 2018


Source:Inorganic Chemistry Communications

Author(s): Evangelos Pilichos, Ioannis Mylonas-Margaritis, Aristotelis P. Kontos, Vassilis Psycharis, Nikolaos Klouras, Catherine P. Raptopoulou, Spyros P. Perlepes

The first use of biacetylmonoxime picolinoylhydrazone in lanthanide(III) chemistry has provided access to a structurally interesting dinuclear praseodymium(III) complex. The ligand undergoes an impressive dysprosium(III)-assisted hydrolysis of its hydrazone and oxime functionalities to give a polydentate ligand containing two picolinoyl and two hydrazone moieties.
Graphical abstract




Authors:   Author(s): Evangelos Pilichos, Ioannis Mylonas-Margaritis, Aristotelis P. Kontos, Vassilis Psycharis, Nikolaos Klouras, Catherine P. Raptopoulou, Spyros P. Perlepes
Journal:   Inorganic Chemistry Communications
Year:   2018
Publication date:   10-Jun-2018
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