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Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity [Chemistry]

The generation of highly reactive molecules under controlled conditions is desirable, as it allows exploration of synthetic chemistry and enables spectroscopic studies of such elusive species. We report here on the synthesis and reactivity of a precursor molecule that readily fragments with concomitant expulsion of dinitrogen and anthracene to release the highly reactive sulfur monoxide, a compound of interest for both synthetic chemists and astrochemists.

Authors:   Maximilian Joost; Matthew Nava; Wesley J. Transue; Marie-Aline Martin-Drumel; Michael C. McCarthy; David Patterson; Christopher C. Cummins
Journal:   Proceedings of the National Academy of Sciences current issue
Volume:   115
edition:   23
Year:   2018
Pages:   5866
DOI:   10.1073/pnas.1804035115
Publication date:   05-Jun-2018
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