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Lanthanide-induced relaxation anisotropy

Lanthanide ions accelerate nuclear spin relaxation by two primary mechanisms: dipolar and Curie. Both are commonly assumed to depend on the length of the lanthanide-nucleus vector, but not on its direction. Here we show experimentally that this is wrong – careful proton relaxation data analysis in a series o

Authors:   Elizaveta Suturina; Kevin Mason; Carlos F.G.C. Geraldes; Nicholas F Chilton; David Parker; Ilya Kuprov
Journal:   Physical Chemistry Chemical Physics
DOI:   10.1039/C8CP01332B
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