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Bridging Cyanides from Cyanoiron Metalloligands to Redox-active Dinitrosyl Iron Units

Cyanide, as an ambidentate ligand, plays a pivotal role in providing a simple diatomic building-block motif, for controlled metal aggregation, M-CN-M’. Specifically, the inherent hard-soft nature of the cyanide ligand, i.e., hard-nitrogen and soft-carbon centers, are electronic handles for binding Lewis acid

Authors:   Pokhraj Ghosh; Manuel Quiroz; Randara Pulukkody; Nattamai Bhuvanesh; Marcetta Y. Darensbourg
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01761A
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