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Cross-linking of cyanide magnetic coordination polymers by rational insertion of formate, cyanide or azide

Carefully selected molecular bridging ligands formate, cyanide and azide, that are known to transmit strong magnetic interactions, have been successfully inserted into the {[MnII(H2O)2]2[NbIV(CN)8]·4H2O}n (Mn2Nb) ferrimagnetic parent framework, resulting in the additional molecular bridging of the two MnII centres

Authors:   Gabriela Handzlik; Barbara Sieklucka; Dawid Pinkowicz
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01513A
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  • coordination polymers
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