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Bis(alkylidynyl)arsines

The synthesis and characterization of the first examples of bimetallic bis(alkylidynyl)arsines, [RAs{C≡M(CO)2(Tp*)}2] (M = Mo, R = Ph, Me; M = W, R = Ph, Me, nBu; Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) are described. For the tungsten complexes, these may be prepared by a potentially generalizable r

Authors:   Anthony Hill; Benjamin Frogley
Journal:   Chemical Communication
DOI:   10.1039/C8CC04164D
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