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Catalytic Alkylation Reactions of Weakly Acidic Carbonyl and Related Compounds Using Alkenes as Electrophiles

Catalytic alkylation reactions of weakly acidic carbonyl and related pronucleophiles such as amides, esters, and sulfonamides with substituted alkenes are reported. In the presence of a strong Brønsted base catalyst system, potassium hexamethyldisilazide and 18-crown-10 ether, the desired reactions proceeded Synthetic methodology in OBC

Authors:   Yasuhiro Yamashita; Ryo Igarasgi; Hirotsugu Suzuki; Shu Kobayashi
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB00941D
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  • amides
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