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Metastable quasicrystal-induced nucleation in a bulk glass-forming liquid [Applied Physical Sciences]

A model alloy, Mg69Zn27Yb4, concurrently forms bulk metallic glass, metastable quasicrystals (QCs), and crystalline approximant phases from the melt. We demonstrate that a transient QC phase nucleates first from the melt and subsequently transforms into an equilibrium approximant phase. This nucleation path is likely to be a general mechanism in metastable QC-forming systems. We observed a metastable-to-stable phase transformation when we deployed fast differential scanning calorimetry using the experimental strategy of interrupted cooling after the onset of crystallization followed by heating at ultrafast rates to “up-quench” the previously frozen structure. This strategy can yield the discovery of hidden transient phases that are key to understanding the crystallization behavior in metallic systems, polymers, biological solutions, and pharmaceutical substances.

Authors:   Güven Kurtuldu; Karl F. Shamlaye; Jörg F. Löffler
Journal:   Proceedings of the National Academy of Sciences current issue
Volume:   115
edition:   24
Year:   2018
Pages:   6123
DOI:   10.1073/pnas.1717941115
Publication date:   12-Jun-2018
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