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Synthesis of multi-substituted allenes from organoalane reagents and propargyl esters by nickel-catalyzed

A highly efficient and simple route for the synthesis of multi-substituted allenes has been developed by Nickel catalyzed the SN2’ substitution reaction of propargyl esters with organic aluminium reagents under mild conditions, giving the corresponding product multi-substituted allenes in good to excellent y

Authors:   xuebei shao; Zhen Zhang; Qinghan Li; Zhi-Gang Zhao
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB00781K
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