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Rationalizing the Sign and Magnitude of the Magnetic Coupling and Anisotropy in Dinuclear Manganese(III) complexes

We have synthesised twelve manganese(III) dinuclear complexes, 1-12, in order to understand the origin of magnetic exchange (J) between the metal centres and the magnetic anisotropy (D) of each metal ion using a combined experimental and theoretical approach. All twelve complexes contain the same bridging li

Authors:   Keith S. Murray; Kuduva Vignesh; Gopalan Rajaraman; Stuart K Langley; Craig M Forsyth; Christopher J Gartshore; Ivana Borilovic
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01410H
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