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Hydrophosphination of alkenes and alkynes with primary phosphines catalyzed by zirconium complexes bearing aminophenolato ligands

Zirconium complexes stabilized by amine-bridged bis(phenolato) ligands showed good activity and chemo-selectivity in catalyzing intermolecular hydrophosphination of C–C multiple bonds with primary phosphines under mild conditions. A broad range of alkenes and alkynes underwent a mono-addition reaction with phenylph

Authors:   Yu Zhang; Xinxin Wang; Yaorong Wang; Dan Yuan; Yingming Yao
Journal:   Dalton Transactions
DOI:   10.1039/C8DT02122H
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