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Rhodium-Catalyzed Asymmetric Synthesis of [small beta]-Branched Esters from Allylic Amines

Allylic amines are converted to chiral, β-branched esters under rhodium catalysis in the presence of alcohol nucleophiles. Allylic amines with aliphatic and aromatic vinylic substituents are converted to ester products with excellent enantioselectivities in all cases. Both primary and secondary alcohol nucle

Authors:   Summer D. Laffoon; Zhao Wu; Kami Hull
Journal:   Chemical Communication
DOI:   10.1039/C8CC02612B
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