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Fusing Triphenylphosphine with Tetraphenylborate: Introducing the 9-Phosphatriptycene-10-phenylborate (PTB) Anion

In a fusion of two ubiquitous organometallic reagents, triphenylphosphine (PPh3) and tetraphenylborate (BPh4-); the 9-phosphatriptycene-10-phenylborate (PTB) anion has been prepared for the first time. This borato species has been fully characterized by a suite of spectroscopic methods, and initial reactivit

Authors:   Marcus W. Drover; Koichi Nagata; Jonas C Peters
Journal:   Chemical Communication
DOI:   10.1039/C8CC04321C
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