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Free-Radical Anti-Markovnikov Hydroalkylation of Unactivated Alkenes with Simple Alkanes

A Cu(II)-mediated radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes via selective C(sp3)-H bond cleavage was achieved. This reaction features high site-selectivity, diverse functional group tolerance, and scalability.

Authors:   Yunfei Tian; Anbo Ling; Ren Fang; Ren Xiang Tan; Zhongquan Liu
Journal:   Green Chemistry
DOI:   10.1039/C8GC01394B
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  • alkenes
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