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(2-Fluoroallyl)boronates: new reagents for diastereoselective 2-fluoroallylboration of aldehydes

A Pd-catalyzed borylation of 2-fluoroallyl chlorides with B2pin2 in the presence of [(2-MeAll)PdCl]2/TMEDA or [(2-MeAll)Pd(IPr)Cl] was developed to afford (2-fluoroallyl)pinacolboronates with high Z-selectivity. The products proved to be useful for anti-selective 2-fluoroallylboration of aromatic and aliphat Synthetic methodology in OBC

Authors:   Maxim A. Novikov; Oleg M. Nefedov
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB01103F
Facts, background information, dossiers
  • borylation
  • aldehydes
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