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Transition-metal-free oxidative cyclization of N-propargyl ynamides: stereospecific construction of linear polycyclic N-heterocycles

An efficient NaBArF4-catalyzed oxidative cascade cyclization of N-propargyl ynamides has been developed, where NaBArF4 is demonstrated for the first time to be a highly effective catalyst for promoting such an oxidative cyclization. Importantly, this transition metal-free process strongly supports that this oxidati

Authors:   Cai-Ming Wang; Lin-Jun Qi; Qing Sun; Bo Zhou; Zhi-Xin Zhang; Zai-Fa Shi; Shui-Chao Lin; Xin Lu; Lei Gong; Long-Wu Ye
Journal:   Green Chemistry
DOI:   10.1039/C8GC01534A
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