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Compositional and Structural Insights into the Nature of the H-Cluster Precursor on HydF

Assembly of an active [FeFe]-hydrogenase requires dedicated maturation enzymes that generate the active-site H-cluster: the radical SAM enzymes HydE and HydG synthesize the unusual non-protein ligands - carbon monoxide, cyanide, and dithiomethylamine - while the GTPase HydF serves as a scaffold for assembly

Authors:   Anna G. Scott; Robert K Szilagyi; David W. Mulder; Michael W. Ratzloff; Amanda S. Byer; Paul King; William E. Broderick; Eric M. Shepard; Joan B Broderick
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01654B
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